Application of Response Surface Methodology for Optimization of Methylene Blue Removal by Casuarina equitifolia Leaves Powder

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Dye is a type of colorants that are widely used in many industries. Many dyes are toxic in nature with suspected carcinogenic and mutagenic effects that affect aquatic lives and also human beings. Adsorption process is considered as eco-friendly method to remove color from the aqueous solution compared to other established method. In this study, Casuarina Equitifolia leaves were used as an adsorbent. The Response surface methodology (RSM) was employed, using a central composite design (CCD) to optimize the three important variables, i.e., initial dye concentration, pH of the dye solution and adsorbent dosage in order to remove of methylene blue from aqueous solution. From the analysis of variance (ANOVA), the value (>0.8) of the coefficient of determination (R2) was obtained. The optimal condition was established at pH 6.91, 0.1 g adsorbent dosage and 10ppm initial methylene blue concentration. The removal efficiency was found to be 98.80%. From the findings, it shows that Casuarina Equitifolia leaves powder is suitable to be used as an adsorbent in removal of color from aqueous solution.

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745-750

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July 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. Yasin, M. Z. Hussein, F. H. Ahmad, Adsorption of methylene blue onto treated activated carbon, The Malaysian Journal of Analytical Sciences. 11(2007) 400 – 406.

Google Scholar

[2] A. S. Ozcan, Adsorption of acid dyes from aqueous solutions onto acid activated bentonite, J. Colloid Interf. Sci. 276 (2) (2004) 39-46.

DOI: 10.1016/j.jcis.2004.03.043

Google Scholar

[3] T. Robinson, G. Mc Mullan, R. Marchant, P. Nigam, Remediation of dyes in textiles effluent: a critical review on current treatment technologies with a proposed alternative, Bioresource Technology. 77 (1) (2001) 247-255.

DOI: 10.1016/s0960-8524(00)00080-8

Google Scholar

[4] G. Mourchid, I. Maghri, M. Elkouali, Removal of Cationic Dye Methylene Blue onto Moroccan Clay, Global Journal of Science Frontier Research Chemistry. 13 (2013).

Google Scholar

[5] Mukhlish, M. R. Khan, M.C. Bhoumic, S. Paul, Papaya (Carica papaya L. ) Leaf Powder: Novel Adsorbent for Removal of Methylene Blue from Aqueous Solution, Water, Air, & Soil Pollution. 223(8) (2012) 4949-4958.

DOI: 10.1007/s11270-012-1249-7

Google Scholar

[6] M. Rafatullah, O. Sulaiman, R. Hashim, A. Ahmad, Adsorption of Methylene Blue on low-cost adsorbents: a Review, Journal of Hazardous Materials. 177(2010) 70-80.

DOI: 10.1016/j.jhazmat.2009.12.047

Google Scholar

[7] M. Auta, B. H. Hameed, Optimized waste tea activated carbon for adsorption of Methylene Blue and Acid Blue 29 dyes using response surface methodology, Chemical Engineering Journal. 175 (2011) 233-243.

DOI: 10.1016/j.cej.2011.09.100

Google Scholar

[8] M. Auta and B. H. Hameed, Optimized waste tea activated carbon for adsorption of Methylene Blue and Acid Blue 29 dyes using response surface methodology, Chemical Engineering Journal, vol. 175, p.233–243, Nov. (2011).

DOI: 10.1016/j.cej.2011.09.100

Google Scholar

[9] S. Chatterjee, A. Kumar, S. Basu, and S. Dutta, Application of Response Surface Methodology for Methylene Blue dye removal from aqueous solution using low cost adsorbent, Chemical Engineering Journal, vol. 181–182, p.289–299, Feb. (2012).

DOI: 10.1016/j.cej.2011.11.081

Google Scholar

[10] S. Dutta, A. Bhattacharyya, A. Ganguly, S. Gupta, and S. Basu, Application of Response Surface Methodology for preparation of low-cost adsorbent from citrus fruit peel and for removal of Methylene Blue, Desalination, vol. 275, no. 1–3, p.26–36, Jul. (2011).

DOI: 10.1016/j.desal.2011.02.057

Google Scholar

[11] S. Rao J, Optimization of Biosorption Performance of Casuarina Leaf Powder for the Removal of Lead Using Central Composite Design, Journal of Environmental & Analytical Toxicology, vol. 03, no. 02, (2013).

DOI: 10.4172/2161-0525.1000166

Google Scholar

[12] S. Senthilkumaar, P. R. varadarajab, K. Porkodi, C. V. Subbhuraam, Adsorption of methylene blue onto jute fiber carbon: kinetics and equilibrium studies, Journal of Colloid Interface Science. 284 (2005) 78-82.

DOI: 10.1016/j.jcis.2004.09.027

Google Scholar

[13] B. H. Hameed, Evaluation of papaya seeds as a novel non-conventional low-cost adsorbent for removal of methylene blue, J. Haazard. Mater. 162 (2009) 939-944.

DOI: 10.1016/j.jhazmat.2008.05.120

Google Scholar

[14] B. H. Hameed, Grass waste : a novel sorbent for the removal of basic dye from aqueous solution, J. Hazard. Mater. 166 (2009) 233-238.

DOI: 10.1016/j.jhazmat.2008.11.019

Google Scholar

[15] O. Hamdaoui, Batch study of liquid phase adsorption of methylene blue using cedar sawdust and crushed brick, J. Hazad. Mater. B135 (2006) 264-273.

DOI: 10.1016/j.jhazmat.2005.11.062

Google Scholar