Thermodynamics of Iron Metallothermy

Article Preview

Abstract:

Besides other possible applications, the thermitic compositions based on iron oxides are meant to the achieving of the permanent joints of the railroad tracks. In addition to the iron oxides, the thermitic kit include also the reducing agent – aluminum powder, a carbon source to adjust the percent of this element in the obtained steel and a flux with a view to allow the steel composition and temperature control. The metallothermic process efficiency is given by strictness in the selection of ratio of the thermitic components and mainly in that of the iron oxides types. Their correct dosage makes possible the estimation and rigorous control of the thermal effect of reactions. In this work, using thermodynamic calculations, is analyzed and quantified the development of the thermal effect of the metallothermic reduction reactions of iron oxides depending on the iron oxides proportions in the thermitic composition.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

112-117

Citation:

Online since:

July 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] R. J. Lemire, U. Berner, C. Musikas, D. Palmer, P. Taylor, O. Tochiyama, Chemical Thermodynamics of Iron, (13A) Part 1, OECD Nuclear Energy Agency, Data Bank Issy-les-Moulineaux, France, (2013), pp.92-109.

Google Scholar

[2] A. Akuov, M. Tolumbekov, D. Izbembetov, About the thermodynamics of metallothermy of ferrochrome, Transactions of International conference Nauka I obrazovanie – vedushij factor strategii Kazakhstan 2030, Karaganda, 2008, pp.94-96.

Google Scholar

[3] R. M. Cornell, U. Schwertmann, The Iron Oxides - Structures, Properties, Reactions, Occurences and Uses, Wiley-VCH GmbH & Co. KGaA, (2003, ), pp.29-34.

DOI: 10.1002/3527602097

Google Scholar

[4] Outotec's HSC 6. 12 Chemistry Software, Research Center in Pori, Finland, (1974).

Google Scholar

[5] L. P. Vladimirov, Thermodynamic Calculations of Equilibrium of Metallurgical Reactions, published by Metallurgiya, Moscow (1970).

Google Scholar

[6] V. Iu. Levinski, Phase Diagrams of Metals with Gases, published by Metallurgiya, Moscow, pp.239-261, (1975).

Google Scholar

[7] L. L. Wang, Z. A. Munir, Y.M. Maximov, Review - Thermite reactions: their utilization in the synthesis and processing of materials, Journal of Materials Science, 28 (1993), pp.3693-3708.

DOI: 10.1007/bf00353167

Google Scholar

[8] B. Schwartz, ASM Handbook, Volume 6, Welding Brazing and Soldering, pp.835-838, (1993).

Google Scholar