Synthesis, Photoluminescence and Infrared Emissivity of SnO2 Nanocrystalline Thin Films

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Abstract:

SnO2 nanocrystalline thin films (NCTFs) with high quality and low infrared emissivity were synthesized through a simple hydrothermal process designed by orthogonal design theory. The microstructure, morphology, photoluminescence (PL) property and the infrared emissivity (IRE) property of as-prepared products were characterized by x-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), fluorescence spectrophotometer, and infrared spectroradio meter (ISM) respectively. The results show that two emission peaks are observed in PL spectra, which can be deconvoluted by Gaussian profile fitting into four emission peaks centered at about 380, 420, 460 and 520 nm respectively. The influences of crystallinity, concentration of particles and resistivity on IRE were systematically investigated, revealing that the better crystallinity, higher particle density and better conductivity are favorable for lowering IRE.

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55-61

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July 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] J.X. Tian, Z.Y. Zhang, J.F. Yan, et al, Hydrothermal synthesis and infrared emissivity property of flower-like SnO2 particles, AIP Adv. 4 (2014) 047131.

DOI: 10.1063/1.4873536

Google Scholar

[2] K.W. Sun, W.C. Zhou, X.F. Tang, et al, Effects of air annealing on the structure, resistivity, infrared emissivity and transmission of indium tin oxide films, Surf. Coat. Technol, 206 (2012) 4095-4098.

DOI: 10.1016/j.surfcoat.2012.04.001

Google Scholar

[3] D.M. Zhu, K. Li, F. Luo, et al, Preparation and infrared emissivity of ZnO: Al (AZO) thin films, Appl. Surf. Sci, 255 (2009) 6145-6148.

DOI: 10.1016/j.apsusc.2009.01.068

Google Scholar

[4] K.K. Wang, B. Cheng, B. Wu, C. Defranoux, P. Basa, C. Song, G. Han and Y. Liu. Study of annealing effects upon the optical and electrical properties of SnO2: F/SiCxOy low emissivity coatings by spectroscopic ellipsometry,. Thin Solid Films. (2014).

DOI: 10.1016/j.tsf.2013.11.029

Google Scholar

[5] Q. Gao, C.L. Song and G.R. Han, A bi-layer glass-coating for low-e property and photocatalytic activity, J. Aust. Ceram. Soc, 48 (2012) 115-121.

Google Scholar

[6] Q.X. Tian and S.C. Liu, Fabrication and spectral reflective properties of In2O3/SnO2 film, Acta Phys. Sinica, 59 (2010) 541-544.

Google Scholar

[7] S.P. Gong, J. Xia, J.Q. Liu, et al, Highly sensitive SnO2 thin film with low operating temperature prepared by sol–gel technique, Sensor Actuat B-Chem, 134 (2008) 57-61.

DOI: 10.1016/j.snb.2008.04.010

Google Scholar

[8] S. Bansal, D.K. Pandya, S.C. Kashyap, et al, Growth ambient dependence of defects, structural disorder and photoluminescence in SnO2 films deposited by reactive magnetron sputtering, J. Alloys Compd, 583 (2014) 186-190.

DOI: 10.1016/j.jallcom.2013.08.135

Google Scholar

[9] Y.L. Wang, M. Guo, M. Zhang, et al, Facile synthesis of SnO2 nanograss array films by hydrothermal method, Thin Solid Films, 518 (2010) 5098-5103.

DOI: 10.1016/j.tsf.2010.03.003

Google Scholar

[10] M. Wang, Y.F. Gao, L. Dai, et al, Influence of surfactants on the morphology of SnO2 nanocrystals prepared via a hydrothermal method, J. Solid State Chem, 189 (2012) 49-56.

DOI: 10.1016/j.jssc.2012.01.021

Google Scholar

[11] J. Jeong, S.P. Choi, C. I Chang, et al, Photoluminescence properties of SnO2 thin films grown by thermal CVD, Solid State Commun, 127 (2003) 595-597.

DOI: 10.1016/s0038-1098(03)00614-8

Google Scholar

[12] Y.C. Her, J.Y. Wu, Y.R. Lin, et al, Low-temperature growth and blue luminescence of SnO2 nanoblades, Appl. Phys. Lett, 89 (2006) 043115.

DOI: 10.1063/1.2235925

Google Scholar

[13] V. Rajendran and K. Anandan, Size, morphology and optical properties of SnO2 nanoparticles synthesized by facile surfactant-assisted solvothermal processing, Mater. Sci. Semicond. Process, 15 (2012) 393-400.

DOI: 10.1016/j.mssp.2012.01.002

Google Scholar

[14] G.G. Khan, S. Ghosh and K. Mandal, Origin of room temperature d0 ferromagnetism and characteristic photoluminescence in pristine SnO2 nanowires, J. Solid State Chem, 186 (2012) 278-282.

DOI: 10.1016/j.jssc.2011.11.038

Google Scholar

[15] H.J. Yu, G.Y. Xu, X.M. Shen, et al, Low infrared emissivity of polyurethane/Cu composite coatings, Appl. Surf. Sci, 255 (2009) 6077-6081.

DOI: 10.1016/j.apsusc.2009.01.019

Google Scholar