Nanoclay as Anti-Blistering Agent in Polyester Based Coating: Effect of Sea Water and Distilled Water Exposure

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This study was conducted to investigate the effect of nanoclay on hardness, pull off and blistering effect of polyester based coating. Polyester coat, nanoclay and hardener (MEKP) were mixed and mechanically stirred for one hour at ambient temperature at a shear rate of 1000 rpm. Prepared coating was then applied on the surface of plywood for the characterization of the hardness and pull off strength and for the observation of blistering effect towards sea and distilled water. As a result, 6% nanoclay loading gives better hardness strength which is 65% increment from unmodified polyester. However, the pull off strength shows that 2% of nanoclay loading gives higher strength among others with 114% increment compared to unmodified polyester coating. Blister was mostly observed at samples without nanoclay loading for both sea water and distilled water. While the less blistering effect was present at 2% nanoclay loading for sea water and 4% nanoclay loading for distilled water. The presence of nanoclay within the coating improves its bonding ability and the decreasing the micro space within the polymer. Blistering effect for highest and lowest frequency was observed by electron scanning microscope (SEM).

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111-115

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July 2015

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© 2015 Trans Tech Publications Ltd. All Rights Reserved

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[1] Anonymous: Gelcoat blisters, Diagnosis, repair and prevention. Gougeon Brothers, Inc. Bay City, MI (2007).

Google Scholar

[2] A. Mathiazhagan, and R. Joseph: Nanotechnology-A new prospective in organic coating: Review. International journal of chemical engineering and application. Vol. 2 (2011), pp.225-237.

DOI: 10.7763/ijcea.2011.v2.108

Google Scholar

[3] C. Sanchez, and F. Ribot, In: Proceedings of the first European workshop on hybrid organic -inorganic materials. New journal of chemistry, France (1993).

Google Scholar

[4] K.V.P. Chakradhar, K.V. Subbaiah, M.A. Kumar, G. R Reddy: Epoxy/polester blend nanocomposites: Effect of nanoclay on mechanical, thermal and morphological properties. Malaysian polymer journal. Vol 6 (2) (2011), pp.109-118.

Google Scholar

[5] J.W. Rhim: Effect of clay contents on mechanical and water vapour berrier properties of agar- based nanocomposites films. Carbohydrate polymers. Vol. 86 (2011), pp.691-69.

DOI: 10.1016/j.carbpol.2011.05.010

Google Scholar