Waste Solid Byproducts of Microalgae Oil Made into Green Energy

Article Preview

Abstract:

Microalgae have rich oil production under full photosynthesis, which reaches over 50 mass%. In addition, microalgae oil contains the prolific cis-4,7,10,13,16,19-docosahexaenoic acid (DHA) that is usually refined for making health food or food additives. This study investigated Aurantiochytrium sp., which is a kind of microalgae, the oil of which is also refined for use in health food or food additives. The solid byproducts of Aurantiochytrium sp. oil are more than 20 mass%, discarded as rubbish. Fortunately, the solid byproducts have been found to contain a large amount of palmitic acid that exceeds more than 67 mass%, but it is difficult to transesterify from the solid byproducts of Aurantiochytrium sp. oil, such as the waste cooking oil or waste engine oil, which contain many impurities. Therefore, the sequences of saponification, reduction reaction, and acid-catalyzed reactions were conducted for the full process of transesterification in this study. Overall, we have successfully obtained more than 92 mass% transesterification rate from the solid byproducts of Aurantiochytrium sp. oil. The solid byproducts are waste turned into gold.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 1120-1121)

Pages:

208-211

Citation:

Online since:

July 2015

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2015 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

[1] I. Fedorova-Dahms, P. A. Marone, M. Bauter and A. S. Ryan: Safety evaluation of DHA-rich Algal Oil from Schizochytrium sp., Food Chem. Toxicol., 2011, 49, 3310–3318.

DOI: 10.1016/j.fct.2011.08.024

Google Scholar

[2] X. X. Pan, L. Xu, Y. Zhang, X. Xiao, X. F. Wang, Y. Liu, H. J. Zhang and Y. J. Yan: Efficient display of active Geotrichum sp. lipase on pichia pastoris cell wall and its application as a whole-cell biocatalyst to enrich EPA and DHA in fish oil, J. Agric. Food Chem., 2012, 60, 9673−9679.

DOI: 10.1021/jf301827y

Google Scholar

[3] Pyle DJ, Garcia RA, Wen Z. Producing docosahexaenoic acid (DHA)-rich algae from biodiesel-derived crude glycerol: effects of impurities on DHA production and algal biomass composition, J. Agric. Food Chem., 2008, 56, 3933–3939.

DOI: 10.1021/jf800602s

Google Scholar

[4] J. Wang, L. Cao and S. Han: Effect of polymeric cold flow improvers on flow properties of biodiesel from waste cooking oil, Fuel, 2014, 117, 876–881.

DOI: 10.1016/j.fuel.2013.10.006

Google Scholar

[5] P. Sivakumar, K. Anbarasu and S. Renganathan: Bio-diesel production by alkali catalyzed transesterification of dairy waste scum, Fuel, 2011, 90, 147–151.

DOI: 10.1016/j.fuel.2010.08.024

Google Scholar

[6] S. U. Lee, K. Jung, G. W. Park, C. Seo, Y. K. Hong, W. H. Hong and H. N. Chang: Bioprocessing aspects of fuels and chemicals from biomass, Korean J. Chem. Eng., 2012, 29(7), 831–850.

DOI: 10.1007/s11814-012-0080-6

Google Scholar

[7] A. Hayyan, M. A. Hashim, M. E. Mirghani, M. Hayyan and I. M. AlNashef: Esterification of sludge palm oil using trifluoromethane sulfonic acid for preparation of biodiesel fuel, Korean J. Chem. Eng., 2013, 30(6), 1229–1234.

DOI: 10.1007/s11814-013-0045-4

Google Scholar

[8] S. K. Hoekman, A. Broch, C. Robbins, E. Ceniceros and M. Natarajan: Review of biodiesel composition, properties, and specifications, Renew. Sust. Energ. Rev., 2012, 16, 143–169.

DOI: 10.1016/j.rser.2011.07.143

Google Scholar

[9] H. L. Lau Nang, C. W. Puah, Y. M. Choo, A. N. Ma and C. H. Chuah: Simultaneous quantification of free fatty acids, free sterols, squalene, and acylglycerol molecular species in palm oil by high-temperature gas chromatography–flame ionization detection, Lipids, 2005, 40(5), 523–528.

DOI: 10.1007/s11745-005-1413-1

Google Scholar

[10] Y. B. Jo, S. H. Park, J. K. Jeon, C. H. Ko, C. Ryu and Y. K. Park: Biodiesel production via the transesterification of soybean oil using waste starfish (Asterina pectinifera) , Appl. Biochem. Biotechnol, 2013, 170, 1426–1436.

DOI: 10.1007/s12010-013-0279-y

Google Scholar

[11] Y. B. Man Che, G. Setiowaty and F. R. van de Voort: Determination of iodine value of palm oil by Fourier transform infrared spectroscopy, J. Am. Oil. Chem. Soc., 1999, 76(6), 693–699.

DOI: 10.1007/s11746-999-0161-9

Google Scholar