The Formation and Characterization of Poly (p-phenylene benzobisoxazole) Pulps via Stirred Solutions

Rong Biao Liu; Xin Xin Li; Jun Qian; Zhe Wen Han

doi:10.4028/www.scientific.net/AMR.1120-1121.620

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 1120-1121The Formation and Characterization of Poly...

The Formation and Characterization of Poly (p-phenylene benzobisoxazole) Pulps via Stirred Solutions

Abstract:

PBO (p-phenylene benzobisoxazole) short fibers, attached fine fibrils that are called PBO pulp, may precipitate directly from stirred PBO/methanesulfonic acid (MSA) solution by the use of water coagulant in fibrous pulp form. Scanning electron micrographs show that the precipitated PBO pulps have a ribbon-like structure similar to Kevlar pulps. The thermalgravimetric analysis (TGA) show there were no appreciable mass changes until 550 °C in the air. The process yields PBO pulps with different specific surface areas (SSA) depending on the stirring speed, stirring time and the concentration of the PBO/MSA solution. High SSA PBO pulps can be produced by increasing the stirring speed, prolonging the stirring time and reducing the concentration of the PBO/MSA solution.

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Periodical:

Advanced Materials Research (Volumes 1120-1121)

Pages:

620-623

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1120-1121.620

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Online since:

July 2015

Authors:

Rong Biao Liu, Xin Xin Li, Jun Qian, Zhe Wen Han*

Keywords:

Induced Precipitation, Morphology, Poly (p-phenylene benzobisoxazole) pulp (PBO pulp)

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References

[1] J. F. Wolfe, B. H. Loo, F. E. Arnold, Macromolecules. 14 (1981) 915-920.

Google Scholar

[2] J. F. Wolfe, F. E. Arnold, Macromolecules. 14 (1981) 905-915.

Google Scholar

[3] C. Hahn, Journal Industrial Textiles. 30 (2000) 157-163.

Google Scholar

[4] David E. Hoiness, Kevlar aramid pulp, a short fiber reinforcement to replace asbestos. 32nd International SAMPE Symposium. Nat's Academies Press, Boston (1987).

Google Scholar

[5] B. J. Ma, J. Zhu, Tribology, 20 (2000) 260-263 (in Chinese, with English abstract).

Google Scholar

[6] H. T. Guo, Z. G. Zhang, Acta Material Composition Sinica, 18 (2001) 50-54 (in Chinese, with English abstract).

Google Scholar

[7] X. D. Hu, S. E. Jenkins, B. G. Min, M. B. Polk and S. Kumar, Macromolecular Materials and Engineering. 288 (2003) 823-830.

Google Scholar

[8] GB 2596-81 of People's Republic of China.

Google Scholar

[9] G. B. Carter, V. T. J. Schenk, in Structure and Properties of Oriented Polymers, Ed. I. M. Ward (John Wiley, New York, 1975), pp.454-492.

Google Scholar

[10] Q. Fu, H. Zhang, B. Song, X. Liu, Q. Zhuang, Z. Han, Journal of Applied Polymer Science, 121 (2011) 1734-1739.

Google Scholar