Suitability of Malaysian Fly Ash for Geopolymer Synthesis

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Fly ash is a pozzolanic material which is produced during coal combustion in thermal power plants. This paper investigates the suitability of Malaysian fly ash for geopolymer synthesis. Chemical composition analysis, particle size analysis, amorphous and crystalline phases present, bonding nature, and microstructural behavior are used to determine the suitability of fly ash for geopolymer synthesis. The results showed that fly ash contains silica, alumina, ferrous oxide, and calcium oxide in major proportions which are the main ingredients required for geopolymer synthesis. Higher portion of particles having size in the range of 1-15 µm. Fly ash contains quartz, mullite, and ferrite as the crystalline compounds while the major portion of fly ash is in amorphous form. The band due to asymmetric stretching vibration mode of Si-O-T appears at 1095 cm-1 which is the main band used to follow geopolymer formation. Microstructure of fly ash shows that the higher portion of fly ash is in amorphous form while it contains cenospheres, magnetic spheres, carbon, and a large number of small particles. Malaysian fly ash is a suitable material for geopolymer and it can be used for geopolymer synthesis.

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201-205

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January 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Ahmaruzzaman, A review on the utilization of fly ash, Progress in Energy and Combustion Science, 36 (2010) 327-363.

DOI: 10.1016/j.pecs.2009.11.003

Google Scholar

[2] O. Ozdemir, B. Ersoy, and M. S. Celik, Separation of pozzolonic material from lignitic fly ash of Tuncbilek Power Station, in International Ash Utilization Symposium, (2001) 216-234.

Google Scholar

[3] T. A. Kassim and B. R. Simoneit, Environmental impact assessment: principles, methodology and conceptual framework: Springer, (2005).

Google Scholar

[4] A. Committee, ASTM C 618 Standard Specification for Coal Fly Ash and Raw or Calcined Natural Pozzolan for Use as a Mineral Admixture in Concrete, Annual Book of ASTM Standard, Section, 4, (2004).

DOI: 10.1520/c0618-15

Google Scholar

[5] R. P. Williams and A. Van Riessen, Determination of the reactive component of fly ashes for geopolymer production using XRF and XRD, Fuel, 89, 3683-3692, (2010).

DOI: 10.1016/j.fuel.2010.07.031

Google Scholar

[6] V. S. Somerset, Master Dissertation, University of the Western Cape, (2003).

Google Scholar

[7] E. Diaz, E. Allouche, and S. Eklund, Factors affecting the suitability of fly ash as source material for geopolymers, Fuel, 89 (2010) 992-996.

DOI: 10.1016/j.fuel.2009.09.012

Google Scholar

[8] E. Deir, B. S. Gebregziabiher, and S. Peethamparan, Influence of starting material on the early age hydration kinetics, microstructure and composition of binding gel in alkali activated binder systems, Cement and Concrete Composites, 48 (2014).

DOI: 10.1016/j.cemconcomp.2013.11.010

Google Scholar

[9] J. Van Jaarsveld, J. Van Deventer, and G. Lukey, The characterisation of source materials in fly ash-based geopolymers, Materials Letters, 57 (2013) 1272-1280.

DOI: 10.1016/s0167-577x(02)00971-0

Google Scholar

[10] E. M. Van der Merwe, C. L. Mathebula, and L. C. Prinsloo, Characterization of the surface and physical properties of South African coal fly ash modified by sodium lauryl sulphate (SLS) for applications in PVC composites, Powder Technology, 266 (2014).

DOI: 10.1016/j.powtec.2014.06.008

Google Scholar

[11] M. I. Khan, K. Azizli, S. Sufian, and Z. Man, Sodium silicate-free geopolymers as coating materials: Effects of Na/Al and water/solid ratios on adhesion strength, Ceramics International, 41 (2015) 2794-2805.

DOI: 10.1016/j.ceramint.2014.10.099

Google Scholar

[12] A. Fernández-Jiménez and A. Palomo, Mid-infrared spectroscopic studies of alkali-activated fly ash structure, Microporous and Mesoporous Materials, 86 (2005) 207-214.

DOI: 10.1016/j.micromeso.2005.05.057

Google Scholar

[13] A. A. Siyal, L. Ismail, Z. Man, and K. A. Azizli, Effect of NaOH and Water Contents on Solidification of Sodium Silicate Free Geopolymer, in Applied Mechanics and Materials, 2014, 3-6.

DOI: 10.4028/www.scientific.net/amm.625.3

Google Scholar

[14] I. Ismail, S. A. Bernal, J. L. Provis, R. San Nicolas, S. Hamdan, and J. S. van Deventer, Modification of phase evolution in alkali-activated blast furnace slag by the incorporation of fly ash, Cement and Concrete Composites, 45 (2014) 125-135.

DOI: 10.1016/j.cemconcomp.2013.09.006

Google Scholar

[15] R. Blissett and N. Rowson, A review of the multi-component utilisation of coal fly ash, Fuel, 97 (2012) 1-23.

DOI: 10.1016/j.fuel.2012.03.024

Google Scholar