Influence of Silanized-Silica and Carbon Black on the Cure and Mechanical Properties of Natural Rubber/Recycled Chloroprene Rubber (NR/rCR) Blends

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The loadings effect of carbon black and silanized-silica filled 75/25 phr/phr of natural rubber/recycled chloroprene rubber (NR/rCR) blends were compared with the unfilled NR/rCR blends. Different filler loading between in the range of 10- 40 phr was used. The rubber blends were prepared by using a laboratory two-roll mill and rheometric characteristics were studied using the Monsanto moving die rheometer (MDR 2000) at 150 °C. The addition of CB and silanized-silica showed different trend in scorch and cure time but showed similar trend in torques. The incorporation of both fillers caused higher tensile strength than that unfilled rubber blends. By comparison, the silanized-silica filled NR/rCR blends showed higher tensile strength than CB filled NR/rCR blends. Morphological characterization as observed from SEM justified these results.

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191-195

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January 2016

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© 2016 Trans Tech Publications Ltd. All Rights Reserved

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[1] T.D. Sreeja, S.K.N. Kutty, Cure characteristics and mechanical properties of natural rubber/reclaimed rubber blends, Polym. -Plast. Technol. Eng. 39(3) (2000) 501-512.

DOI: 10.1081/ppt-100100043

Google Scholar

[2] J. Clarke, B. Clarke, P.K. Freakley, I. Sutherland, Compatibility effect of carbon black on morphology of NR-NBR blends, Plast. Rub. Comp. 30(1) (2001) 39-44.

DOI: 10.1179/146580101101541426

Google Scholar

[3] M.T. Ramesan, The effect of filler content on cure and mechanical properties of dichlorocarbene modified styrene butadiene rubber/carbon black composites, J. Polym. Res. 11 (2004) 333-340.

DOI: 10.1007/s10965-005-6571-y

Google Scholar

[4] A.T. Petroula, Reinforced elastomers: interphase modification and compatibilization in rubber-based nanocomposites, in: P.M. Visakh, S. Thomas, A.K. Chandra, A.P. Mathew (Eds. ), Advances in Elastomers II: Composites and Nanocomposites, Springer Science & Business Media, Heidelberg, 2013, pp.109-154.

DOI: 10.1007/978-3-642-20928-4_4

Google Scholar

[5] P. Sae-Oui, C. Sirisinha, U. Thepsuwan, K. Hatthapanit, Roles of silane coupling agents on properties of silica-filled polychloroprene, Euro. Polym. J. 42 (2006) 479-486.

DOI: 10.1016/j.eurpolymj.2005.09.003

Google Scholar

[6] S.J. Park, K.S. Cho, Filler-elastomer interactions: influence of silane coupling agent on crosslink density and thermal stability of silica/rubber composites, J. Colloid. Interf. Sci. 267 (2003) 86-91.

DOI: 10.1016/s0021-9797(03)00132-2

Google Scholar

[7] S.Z. Salleh, H. Ismail, Z. Ahmad, Study on the effect of virgin and recycled chloroprene rubber (vCR and rCR) on the properties of natural rubber/chloroprene rubber (NR/CR) blends, J. Polym. Eng. 33 (2013) 803-811.

DOI: 10.1515/polyeng-2013-0127

Google Scholar

[8] H. Ismail, R. Nordin, The effect of filler loading on curing and mechanical properties of natural rubber/recycled rubber powder blends, Inter. J. Polym. Mater. 54 (2005) 9-20.

DOI: 10.1080/00914030390224256

Google Scholar

[9] N.R. Kumar, B.R. Gupta, A.K. Bhowmick, Rheological behavior of acrylic and epoxidised natural rubbers, J. Polym. Eng. 13 (1994) 105-124.

DOI: 10.1515/polyeng.1994.13.2.105

Google Scholar

[10] S. Bandyopadhyay, P.P. De, D.K. Tripathy, S.K. De, Dynamic mechanical spectroscopic studies on the miscibility of polychloroprene-epoxidized natural rubber blend in presence of carbon black, Polym. 36 (10) (1995) 979-(1984).

DOI: 10.1016/0032-3861(95)91441-9

Google Scholar

[11] N. Rattanasom, T. Saowapark, C. Deeprasertkul, Reinforcement of natural rubber with silica/carbon black hybrid filler, Polym. Test. 26 (2007) 369-377.

DOI: 10.1016/j.polymertesting.2006.12.003

Google Scholar

[12] P. Sae-Oui, U. Thepsuwan, K. Hatthapanit, Dependence of mechanical and aging properties of chloroprene rubber on silica and ethylene thiourea loadings, Euro. Polym. J. 43 (2007)185-193.

DOI: 10.1016/j.eurpolymj.2006.10.015

Google Scholar

[13] J. Frohlich, W. Niedermeier, H. -D. Luginsland, The effect of filler-filler and filler-elastomer interaction on rubber reinforcement, Compos. Part A-Appl. S. 36 (2005) 449-460.

DOI: 10.1016/j.compositesa.2004.10.004

Google Scholar

[14] P. Sae-Oui, C. Sirisinha, C. Wantana, K. Hatthapanit, Influence of silica loading on the mechanical properties and resistance to oil and thermal aging of CR/NR blends, J. App. Polym. Sci. 104 (2007) 3478-3483.

DOI: 10.1002/app.26139

Google Scholar

[15] N.Z. Noriman, H. Ismail, Properties of styrene butadiene rubber (SBR)/recycled acrylonitrile butadiene rubber (NBRr) blends: the effects of carbon black/silica (CB/Sil) hybrid filler and silane coupling agent, Si69, J. App. Polym. Sci. 124 (2012).

DOI: 10.1002/app.34961

Google Scholar

[16] I.S. Saad, M. Sh. Fayed, E.M. Abdel-Bary, Effects of carbon black content on cure characteristics, Mechanical properties and swelling behavior of 80/20 NBR/CIIR blend, 13th International Conference on Aerospace Sciences and Aviation Technology, Paper: ASAT-13-CA-06. (2009).

DOI: 10.21608/asat.2009.23488

Google Scholar

[17] A.R. Azura, S. Ghazali, M. Mariatti, Effects of filler loading and aging time on the mechanical and electrical conductivity properties of carbon black filled natural rubber, J. App. Polym. Sci. 110 (2008) 747-752.

DOI: 10.1002/app.28517

Google Scholar