Paper Titles
Development and Characterization of Amine-Clay Hybrid Adsorbents for CO2 Capture
p.547
Esterification of Corn Silk Fiber to Improve Oil Absorbency
p.552
Catalytic Gasification of Oil Sludge Wastes from Petroleum Industries for Hydrogen Production
p.557
Preparation and Characterization of PVDF-DMAc-Nano SiO2 Distillation Membrane
p.561
Synthesis of Ionic Liquid Polymer Incorporating Activated Carbon for Carbon Dioxide Capture and Separation
p.566
Particle Size Measurement in Waste Water Influent and Effluent Using Particle Size Analyzer and Quantitative Image Analysis Technique
p.571
Friction Properties of Waste Cooking Oil with Banana Peel Broth
p.579
Preparation and Characterization of Lignin from Malaysian Coconut Coir Husk (CCH) as a Potential Precursor in Phenol-Formaldehyde (Phenolic) Resins for the Plastics Industry
p.583
Effects of Pressure and Temperature on the Dissolution of Cellulose in Ionic Liquids
p.588

Synthesis of Ionic Liquid Polymer Incorporating Activated Carbon for Carbon Dioxide Capture and Separation

Article Preview

Abstract:

CO2 capture and separation by ionic liquid is one of the fastest growing branches in ionic liquid technology. The aim of this research was to synthesize the ionic liquid polymer incorporating activated carbon and investigating its performance for CO2 capture and separation. The ionic liquid monomers 1-vinyl-3-ethylimidazolium bromide, [veim][Br] and 1-vinyl-3-ethylimidazolium bis (trifluoromethyl-sulfonyl) imide, [veim][Tf2N] were first synthesized and then polymerized into ionic liquid polymers incorporating activated carbon. The purity of the [veim][Br] and [veim][Tf2N] was verified by 1H NMR, 13C NMR and Ion Chromatography. Both monomers were proved to be in high purity. The elemental composition of both polymer materials synthesized were examined using energy dispersive X-ray spectroscopy (EDX) and the morphology of the synthesized material was observed using field emission scanning electron microscopy (FESEM). The results revealed that activated carbon has been successfully incorporated into the lattice structure of polymer materials. The fabricated polymer materials would be expected to have higher CO2 capture capability as it combines both the absorption and adsorption mechanism for CO2 apprehension and sequestration.

You might also be interested in these eBooks
2nd Advanced Materials Conference 2014 View Preview

Info:

Periodical:

Advanced Materials Research (Volume 1133)

Pages:

566-570

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.1133.566

Citation:

Cite this paper

Online since:

January 2016

Authors:

Hamayoun Mahmood*, Muhammad Hafiz Arif bin Ahmad Sayukhi, Muhammad Moniruzzaman, Suzana Yusup

Keywords:

Carbon Nanotubes, CO2 Capture, Ionic Liquid Polymer

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

© 2016 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

* - Corresponding Author

References

[1] G. Cevasco, C. Chiappe, Are ionic liquids a proper solution to current environmental challenges? Green Chemistry. 16 (2014) 2375- 2385.

DOI: 10.1039/c3gc42096e

Google Scholar

[2] M. Hasib-ur-Rahman, M. Siaj, F. Larachi, Ionic liquids for CO2 capture-Development and progress, Chem. Eng. Process. 49 (2010) 313-322.

DOI: 10.1016/j.cep.2010.03.008

Google Scholar

[3] B. A. Oyenekan, G. T. Rochelle, Energy performance of stripper configurations for CO2 capture by aqueous amines, Ind. Eng. Chem. Res. 45 (2006) 2457- 2464.

DOI: 10.1021/ie050548k

Google Scholar

[4] R. T. Watson, J. Patz, D. J. Gubler, E. A. Parson, J. H. Vincent, Environmental health implications of global climate change, J. Environ. Monit. 7 (2005) 834- 843.

DOI: 10.1039/b504683a

Google Scholar

[5] Z. Zhao, H. Dong, X. Zhang, The research progress of CO2 capture with ionic liquids, Chin. J. Chem. Eng. 20 (2012) 120-129.

Google Scholar

[6] L. M. G. Sanchez, G. W. Meindersma, A. B. de Haan, Solvent properties of functionalized ionic liquids for CO2 absorption, Chem. Eng. Res. Des. 85 (2007) 31-39.

DOI: 10.1205/cherd06124

Google Scholar

[7] A. Heidari, H. Younesi, A. Rashidi, A. A. Ghoreyshi, Evaluation of CO2 adsorption with eucalyptus wood based activated carbon modified by ammonia solution through heat treatment, Chem. Eng. J. 254 (2014) 503-513.

DOI: 10.1016/j.cej.2014.06.004

Google Scholar