Fast Response and Stable Humidity Sensing Performance of La0.9Mg0.1FeO3 Perovskite Material

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Humidity sensors play a vital role in various industrial and environmental monitoring applications that require accurate and stable detection of moisture. In this study, La0.9Mg0.1FeO3 perovskite was synthesized via a sol–gel method, in which Mg2+ ions were substituted at the A-site of lanthanum ferrite to enhance material performance. X-ray diffraction (XRD) analysis confirms the formation of a single-phase orthorhombic perovskite structure with a Pnma space group, indicating successful phase formation without detectable secondary phases. Scanning electron microscopy (SEM) observations reveal a relatively homogeneous surface morphology with nearly spherical or polygonal grains and well-defined grain boundaries. A sensing layer was fabricated by drop-casting the synthesized material onto an interdigital alumina (IDT) substrate, and its capacitance response was measured using an LCR meter over a relative humidity (RH) range of 11%–96% at room temperature. The sensor shows stable performance after 30 days of testing, with response and recovery times of 9.8 s and 1.7 s, respectively. These results suggest that A-site Mg2+ substitution modifies the structural and electrical characteristics of LaFeO3 and supports the potential of La0.9Mg0.1FeO3 for capacitive humidity sensing applications.

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49-55

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July 2026

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© 2026 Trans Tech Publications Ltd. All Rights Reserved

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[1] Z. Duan, M. Xu, T. Li, Y. Zhang, and H. Zou, "Super-fast response humidity sensor based on La0.7Sr0.3MnO3 nanocrystals prepared by PVP-assisted sol-gel method," Sens. Actuators B Chem., vol. 258, p.527–534, Apr. 2018.

DOI: 10.1016/J.SNB.2017.11.169

Google Scholar

[2] Efriyadi, M. A. Dwiputra, and D. Triyono, "Study of humidity sensing properties of TiO2/Ethyl cellulose (EC) composite," Mater. Today Proc., vol. 66, p.2474–2477, Jan. 2022.

DOI: 10.1016/J.MATPR.2022.06.450

Google Scholar

[3] J. Zhao et al., "Highly sensitive humidity sensor based on high surface area mesoporous LaFeO3 prepared by a nanocasting route," Sens. Actuators B Chem., vol. 181, p.802–809, 2013.

DOI: 10.1016/j.snb.2013.02.077

Google Scholar

[4] R. Douani et al., "Improvement of humidity sensing performance of BiFeO3 nanoparticles-based sensor by the addition of carbon fibers," Sens. Actuators A Phys., vol. 307, Jun. 2020.

DOI: 10.1016/j.sna.2020.111981

Google Scholar

[5] M. Kumar, D. V. Singh, S. Dabas, A. N. Srivastva, D. K. Dwivedi, and P. Kumar, "Perspective—Latest Updates and Future Perspectives on Perovskite Materials Based Humidity Sensors," J. Electrochem. Soc., vol. 171, no. 12, p.127508, Dec. 2024.

DOI: 10.1149/1945-7111/ad97e4

Google Scholar

[6] A. Boulahouache, M. Benlembarek, N. Salhi, A. M. Djaballah, C. Rabia, and M. Trari, "Preparation, characterization and electronic properties of LaFeO3 perovskite as photocatalyst for hydrogen production," Int. J. Hydrogen Energy, vol. 48, no. 39, p.14650–14658, May 2023.

DOI: 10.1016/j.ijhydene.2022.12.327

Google Scholar

[7] Y. Guan et al., "Band gap regulation of LaFeO3 via doping Sr for efficient conversion of coke and steam," Ceram. Int., vol. 50, no. 12, p.21526–21537, Jun. 2024.

DOI: 10.1016/J.CERAMINT.2024.03.266

Google Scholar

[8] D. Triyono, R. W. Utami, H. Laysandra, and R. A. Susilo, "Structural, magnetic and electrical properties of La1-xMgxFeO3 perovskites," Ceram. Int., vol. 48, no. 4, p.4595–4603, Feb. 2022.

DOI: 10.1016/j.ceramint.2021.10.246

Google Scholar

[9] J. Qin, Z. Cui, X. Yang, S. Zhu, Z. Li, and Y. Liang, "Three-dimensionally ordered macroporous La1-xMgxFeO3 as high performance gas sensor to methanol," J. Alloys Compd., vol. 635, p.194–202, Jun. 2015.

DOI: 10.1016/j.jallcom.2015.01.226

Google Scholar

[10] A. Herawati et al., "Site-specific Mg doping in LaFeO3 perovskites: Tuning photophysical behavior and trap-state dynamics," Mater. Sci. Semicond. Process., vol. 207, no. 38, p.110507, Jun. 2026.

DOI: 10.1016/j.mssp.2026.110507

Google Scholar

[11] N. N. Elisa Dewi, R. Maulidia, D. Triyono, R. A. Rafsanjani, and I. Sugihartono, "The Influence of Mg Substitution at A and B-Sites on the Structural and Optical Properties of LaFeO3 Perovskites," J. Phys. Conf. Ser., vol. 3139, no. 1, p.012017, 2025.

DOI: 10.1088/1742-6596/3139/1/012017

Google Scholar

[12] R. J. D. Tilley, "Perovskites Structure-Property Relationships," 2016. [Online]. Available: www.wiley.com.

Google Scholar

[13] A. F. F. Alaih, D. Triyono, M. A. Dwiputra, and F. A. A. Nugroho, "Ultrafast and low-hysteresis humidity sensors based on mesoporous LaFe0.925Ti0.075O3 perovskite," Sens. Actuators B Chem., vol. 412, p.135810, Aug. 2024.

DOI: 10.1016/J.SNB.2024.135810

Google Scholar

[14] M. Kumari, N. Dhariwal, P. Yadav, V. Kumar, and O. P. Thakur, "Urea modified Cu-doped LaFeO3 nano-particles for humidity sensing with contactless moisture detection for medical and agricultural application," Sens. Actuators B Chem., vol. 423, Jan. 2025.

DOI: 10.1016/j.snb.2024.136749

Google Scholar

[15] C. Jesica Anjeline and N. Lakshminarasimhan, "Interfacial proton conduction in high-dielectric-constant spinel-perovskite NiFe2O4–LaFeO3 nanocomposite probed by impedimetric humidity sensing," Ceram. Int., vol. 48, no. 21, p.32536–32539, Nov. 2022.

DOI: 10.1016/J.CERAMINT.2022.07.217

Google Scholar