Classification of Glassy and Polymer Electrolytes for Lithium-Ion Batteries by the Bond-Strength-Coordination Number Fluctuation Model

Jean Léopold Ndeugueu; Masaru Aniya

doi:10.4028/www.scientific.net/AMR.123-125.1075

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 123-125Classification of Glassy and Polymer Electrolytes...

Classification of Glassy and Polymer Electrolytes for Lithium-Ion Batteries by the Bond-Strength-Coordination Number Fluctuation Model

Abstract:

This article deals with the classification of glassy and polymer electrolytes for lithium-ion batteries into the so-called “strong/fragile” scale, by the means of the bond-strength-coordination number fluctuation model. We have evaluated the strength parameter, which plays a key role in the understanding of the relaxation phenomena, of each lithium-ion conductor under consideration. We have derived a relationship that not only describes accurately the experimental results, but also provides important details on the interrelation between the strength parameter, the bond strength of the structural unit, the binding energy, the coordination number and the glass transition temperature.

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Periodical:

Advanced Materials Research (Volumes 123-125)

Pages:

1075-1078

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.123-125.1075

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Online since:

August 2010

Authors:

Jean Léopold Ndeugueu, Masaru Aniya

Keywords:

Fragility Index, Glass Transition Temperature (T_g), Glass-Forming Liquids, Strength Parameter

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