Novel Biodegradable Polyurethane Foams Synthesized via Ring-Opening Oligomerization of Ethylene Carbonate Initiated / Catalyzed by Propylene Glycol / [bmim]Cl-(SnCl2) System

Jian Cheng Zhou; Ling Cheng; Dong Fang Wu

doi:10.4028/www.scientific.net/AMR.146-147.1451

Paper Titles

Influence of Electrode Argon-Hydrogen Co-Injection on Carbon Content in Ladle Furnace
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Effect of Ti and Zr Deoxidation on Inclusions and Microstructure of Low Carbon Steel
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Study on MgO-Al₂O₃-TiO₂ Inclusion in 409L Stainless Steel
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Measurement and Analysis of Fabric Capillary Radius Distribution
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Novel Biodegradable Polyurethane Foams Synthesized via Ring-Opening Oligomerization of Ethylene Carbonate Initiated / Catalyzed by Propylene Glycol / [bmim]Cl-(SnCl₂) System
p.1451

Measurement and Estimation of Yarn Pore Size Distribution by Gravity Class
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Fractional Exponent of the Modified Stokes-Einstein Relation in the Metallic Glass-Forming Melt Pd₄₃Cu₂₇Ni₁₀P₂₀
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The Relevant Technology Research on Heat Balance Control of Aluminum Reduction Cell
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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 146-147Novel Biodegradable Polyurethane Foams Synthesized...

Novel Biodegradable Polyurethane Foams Synthesized via Ring-Opening Oligomerization of Ethylene Carbonate Initiated / Catalyzed by Propylene Glycol / [bmim]Cl-(SnCl₂) System

Abstract:

Poly ether-carbonate diols were synthesized by ring-opening oligomerization of ethylene carbonate (EC) initiated/catalyzed by propylene glycol/[bmim]Cl-(SnCl2) system. It was shown that the oligomerization was accompanied with decarboxylation and chain cleavage. The stronger the lewis acidity of ionic liquid, the better the catalytic performances. The biogradability of the polyurethane foams which was prepared by poly ether-carbonate diols (or common polyether polyos ZS-4110) and diphenylmethane diisocyanate (MDI) was determined by soil burial and found to be influenced by the content of carbonate unit, molecular weights and the hydroxyl value of polyols respectively. Poly ether-carbonate diols can reduce the amount of MDI in synthesis of polyurethane foams.

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Periodical:

Advanced Materials Research (Volumes 146-147)

Pages:

1451-1457

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.146-147.1451

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Online since:

October 2010

Authors:

Jian Cheng Zhou, Ling Cheng, Dong Fang Wu

Keywords:

Biodegradation, Ethylene Carbonate, Ionic Liquid (IL), Poly Ether-Carbonate Diols, Polyurethane (PU), Ring-Opening Oligomerization

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