Green Catalyzing Transesterification of Soybean Oil with Methanol for Biodiesel Based on the Reuse of Waste River-Snail Shell

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In this paper, calcined river-snail shell was used as a novel solid base catalyst in the transesterification of soybean oil with methanol for biodiesel production. The calcined river-snail shell was characterized using field emission scanning electron microscope and X-ray diffraction. Effects of transesterification process variables were investigated. The results indicated that river-snail shell calcined at 800 °C catalyzed the transesterification of soybean oil for biodiesel with a yield over 98 % under the conditions including catalyst of 3.0% (w/w), a molar ratio of methanol/oil of 9:1, reaction time of 3 h, and reaction temperature of 65 °C. As a low-cost green catalyst, calcined river-snail shell could not only minimize the environmental wastes resulted from the solid shell, but also reduce the production costs of biodiesel.

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Advanced Materials Research (Volumes 148-149)

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794-798

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October 2010

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] Y. C. Sharma, B. Singh: Fuel Vol. 87 (2008), p.1740.

Google Scholar

[2] D. Y. C. Leung, Y. Guo: Fuel Process Technol. Vol. 87 (2006), p.883.

Google Scholar

[3] F. Ma, M. A. Hanna: Bioresour. Technol. Vol. 70 (1999), p.1.

Google Scholar

[4] A. Srivastava, R. Prasad: Renewable Sustainable Energy Rev. Vol. 4 (2000), p.111.

Google Scholar

[5] B. K. Barnwal, M. P. Sharma: Renewable Sustainable Energy Rev. Vol. 9 (2005) p.363.

Google Scholar

[6] M. L. Granados, M. D. Z. Poves, D. M. Alonso, R. Mariscal, F.C. Galisteo, R. Moreno-Tost, J. Santamaría, J. L. G. Fierro: Appl. Catal. B-Environ. Vol. 73 (2007), p.317.

DOI: 10.1016/j.apcatb.2006.12.017

Google Scholar

[7] L. Wang, J. Yang: Fuel Vol. 86 (2007), p.328.

Google Scholar

[8] X. Liu, H. He, Y. Wang, S. Zhu, X. Piao: Fuel Vol. 87 (2008), p.216.

Google Scholar

[9] P. Chuayplod, W. Trakarnpruk: Ind. Eng. Chem. Res. Vol. 48 (2009), p.4177.

Google Scholar

[10] W. Xie, X. Huang: Catal. Lett. Vol. 107 (2006), p.53.

Google Scholar

[11] S. Furuta, H. Matsuhashi, K. Arata: Biomass Bioenerg. Vol. 30 (2006), p.870.

Google Scholar

[12] W. Xie, H. Peng, L. Chen: Appl. Catal. A: Gen. Vol. 300 (2006), p.67.

Google Scholar

[13] M. C. G. Albuquerque, I. Jiménez-Urbistondo, J. Santamaría-González, J. M. Mérida-Robles, R. Moreno-Tost, E. Rodríguez-Castellón, A. Jiménez-López, P. Maireles-Torres: Appl. Catal. A: Gen. Vol. 334 (2008), p.35.

DOI: 10.1016/j.apcata.2007.09.028

Google Scholar

[14] N. Nakatani, H. Takamori, K. Takeda, H. Sakugawa: Bioresour. Technol. Vol. 100 (2009), p.1510.

Google Scholar

[15] Z. Wei, C. Xu, B. Li: Bioresour. Technol. Vol. 100 (2009), p.2883.

Google Scholar

[16] P. L. Boey, G. P. Maniama, S. A. Hamid: Bioresour. Technol. Vol. 100 (2009), 6362.

Google Scholar

[17] L. G. Yang, A. Q. Zhang, X. S. Zheng: Energ. Fuel. Vol. 23 (2009), p.3859.

Google Scholar