The Influence of Purification of Ethyl Acrylate on the Properties of Cement Matrix

Article Preview

Abstract:

This research mainly probes into the analysis of performance and assessment that ethyl acrylate polymer is applied to the cement matrix. The result shows that, before and after the purification, ethyl acrylate can increase the flowability of modified mortar, and with the increasing the dosage of polymer, the flowability is getting better. But if the dosage of hydrogen peroxide used to remove the residua alcohol is excessive, it is easy to cause high mortar viscosity, and that is unfavorable to the flowability. According to the setting time of the mortar under normal consistency, the result shows that the ethyl acrylate before the purification, has retarding effects on both initial and final setting time. With the increasing the dosage of polymer, it takes longer for both setting time. Besides, because hydrogen peroxide has accelerative effect, the purified ethyl acrylate can shorten the setting time of initial and final setting time. However, over dosage of hydrogen peroxide can easily lead to poor strength development in later stage. Using purified ethyl acrylate can overcome the shortcoming of lower strength of 3、7- day early stage. when hydrogen peroxide consumption is 0.5% of the total amount of acid and alcohol, the ethyl acrylate has the positive effect on improving the compressive strength. Finally, among the comprehensive assessments of the mortar testing results, EH0.5-0.1 has the significant effect of modification.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 150-151)

Pages:

1143-1151

Citation:

Online since:

October 2010

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Fowler, D.W., Polymer in concrete : a vision for the 21st century, Cement and Concrete Composites, Vol. 21, No. 5, pp.449-452 (1999).

DOI: 10.1016/s0958-9465(99)00032-3

Google Scholar

[2] Ohama, Y., Recent progress in concrete-polymer composites, Advn Cem Bas Mat., Vol. 5, pp.31-40 (1997).

Google Scholar

[3] Ohama, Y., Polymer-based admixyures, Cement and Concrete Composites, Vol. 20, NO. 2, pp.189-212 (1998).

Google Scholar

[4] Afridi, M. U. K., Ohama, Y., Demura, K., and Iqbal, M. Z., Development of polymer films by the coalescence of polymer particles in powdered and aqueous polymer-modified mortars, Cement and Concrete Research, Vol. 33, No. 11, pp.1715-1721 (2003).

DOI: 10.1016/s0008-8846(02)01094-3

Google Scholar

[5] Schulze, J., and Killermann, O., Long-term performance of redispersible powders in mortars, Cement and Concrete Research, Vol. 31, No. 3, pp.357-362 (2001).

DOI: 10.1016/s0008-8846(00)00498-1

Google Scholar

[6] Afridi, M. U. K., Ohama, Y., Demura, K., and Iqbal, M. Z., A note on the comparison of crack resistance of Ca(OH)2 crystals of unmodified and polymer-modified mortars in carbonated atmosphere, Cement and Concrete Research, Vol. 31, No. 11, pp.1643-1645 (2001).

DOI: 10.1016/s0008-8846(01)00600-7

Google Scholar

[7] Al-Zahrani, M. M., Maslehuddin, M., Al-Dulaijan, S. U., and Ibrahim, M., Mechanical properties and durability characteristics of polymer- and cement-based repair materials, Cement and Concrete Composites, Vol. 25, No. 4, pp.527-537 (2003).

DOI: 10.1016/s0958-9465(02)00092-6

Google Scholar

[8] Afridi, M. U. K., Ohama, Y., Demura, K., and Iqbal, M. Z., Hydrogarent-type cubic crystals in polymer-modified martars, Cement and Concrete Research, Vol. 27, No. 12, pp.1787-1789 (1997).

DOI: 10.1016/s0008-8846(97)00176-2

Google Scholar

[9] Chandra, S., and Flodin, P., Interactions of polymers and organic admixtures on portland cement hydration, Cement and Concrete Research, Vol. 17, No. 6, pp.875-890 (1987).

DOI: 10.1016/0008-8846(87)90076-7

Google Scholar

[10] Sakai, E., and Sugita, J., Composite mechanism of polymer modified cement, Cement and Concrete Research, Vol. 25, No. 1, pp.127-135 (1995).

DOI: 10.1016/0008-8846(94)00120-n

Google Scholar

[11] Mindess, S., Young, J. F., and Darwin, D., Concrete. 2nd ed., Prentice-Hall, Inc., Upper Saddle River, New Jersey, pp.583-598 (2002).

Google Scholar

[12] Fu, X., and Chung, D. L., Submicron carbon filament cement-matrix composites for electromagnetic interference shielding, Cement and Concrete Research, Vol. 26, No. 10, pp.1467-1472 (1996).

DOI: 10.1016/0008-8846(96)00146-9

Google Scholar

[13] Fichet, R. O., Gauthier, C., Clamen, G., and Boch, P., Microstructural aspects in a polymer-modified cement, Cement and Concrete Research, Vol. 28, No. 12, pp.1687-1693 (1998).

DOI: 10.1016/s0008-8846(98)00153-7

Google Scholar

[14] Rha, C. Y., Kim, C. E., Lee, C. S., Kim, K. I., and Lee, S. K., Preparation and characterization of absorbent polymer-cement composites, Cement and Concrete Research, Vol. 29, No. 2, pp.231-236 (1999).

DOI: 10.1016/s0008-8846(98)00186-0

Google Scholar

[15] Rodrigues, F. A., and Joekes, I., Macro-defect free cements-a new approach, Cement and Concrete Research, Vol. 28, No. 6, pp.877-885 (1998).

DOI: 10.1016/s0008-8846(98)00044-1

Google Scholar

[16] Gao, J. M., Qian, C. X., Wang, B., and Morino, K., Experimental Study on Properties of Polymer-Modified Cement Mortars with Silica Fume, Cement and Concrete Research, Vol. 32, No. 1, pp.41-45 (2002).

DOI: 10.1016/s0008-8846(01)00626-3

Google Scholar