Improving Performance of BaCo0.7Fe0.2Nb0.1O3-δ Ceramic Membrane by a Surface-Coating Layer for Partial Oxidation of Coke Oven Gas

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The BaCo0.7Fe0.2Nb0.1O3-δ (BCFNO) membranes combined with Ce0.8Re0.2O2-δ (Re=La, Y) layer on the permeation side were used for hydrogen production by partial oxidation reforming of coke oven gas (COG). The Ce0.8Re0.2O2-δ improved the oxygen permeation flux of the membrane by 11–28% at 750 oC. The high oxygen permeation flux achieved using the Ce0.8Re0.2O2-δ surface-coating layer in this work are quite encouraging with a maximum value reaching 19.7 ml/cm2•min at 900 oC, which will be promising surface modification materials in the catalytic partial oxidation reforming of COG.

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Advanced Materials Research (Volumes 154-155)

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877-881

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October 2010

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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