Synthesis and Characterization of the Ba₅(P_xAs_1-xO₄)₃Cl Solid Solutions

Abstract:

A series of arsenate substituted chlorapatite was directly prepared through aqueous precipitation method. Characterization studies from elemental analysis, XRD, FT-IR spectra and SEM confirmed the forming of the arsenate/phosphate chlorapatite solid solutions. The XRD analysis indicated the typical solid solution phase of the apatite-type structure. In FT-IR spectra, the area of the phosphate peak was gradually suppressed and the arsenate peak increased as the proportion of the arsenate increased. The solids with As/(As+P) molar ratio of 0.49~1.0 were needle-like crystals; those with As/(As+P) molar ratio <0.19 were large tabular.

• Periodical: Advanced Materials Research (Volumes 156-157)
• Pages: 232-236
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.156-157.232
• Online since: October 2010
• Authors: Cai Chun Wei, Yan Pan, Yi Nian Zhu, Zong Lan Zhang, Hui Li Liu, Zong Qiang Zhu
• Keywords: Arsenate, Chlorapatite, Phosphate, Solid Solution

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