Study on Structural Deformation and Performance of Polypropylene Spherulite Prepared by Uniaxial Compression Processing

Article Preview

Abstract:

Mechanical properties have close relation with microstructure. Based on orientation of the molecule chain in fiber, they show a rapid increase in tensile properties. Nevertheless, block materials mainly gain rise of mechanical properties by blend or composite, it is hardly proposed on the self-reinforced materials by optimizing the microstructure. In this paper, a strengthening of PP was gained by uniaxial compression through small deformation of spherulite. A series of measurements were applied, including tensile test, polarizing optical microscope (POM) and differential scanning calorimeter (DSC). The results show that the tensile properties of polypropylene (PP) have a rapid rise. POM suggestes that the spherulite has deformed into ellipsoid even belt along the orientation of sample of PP, which plays an important role in self-reinforcing of PP. And the initial melt point displayed by DSC slightly decreases because of the partial ruptures of crystal phase.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 175-176)

Pages:

308-311

Citation:

Online since:

January 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B.L. Smith: Nature Vol. 399(1999), p.761.

Google Scholar

[2] M.H. Huang: Langmuir Vol. 14(1998), p.7331.

Google Scholar

[3] A. Peterlin: J. Mater. Sci. Vol. 6(1971), p.490.

Google Scholar

[4] C. G'Sell, A. Dahoun: Mater Sci Eng. A Vol. 175(1994), P. 183.

Google Scholar

[5] Z. Bartczak, A.S. Argon, R. E. Cohen: Polymer Vol. 35(1994), p.3427.

Google Scholar

[6] P.S. Hope: Polym. Eng. Sci. Vol. 20(1980), p.540.

Google Scholar

[7] Z. Bartczak, E. Lezak: Polymer Vol. 46(2005), p.6050.

Google Scholar