Influencing Factors of Modified PVDF Grafted onto a Blended PAMPS(PVDF-G-PAMPS) Membrane
A proton exchange membrane of blended poly (acrylamido-2- methylpropane sulfonic acid) grafted onto modified poly (vinylidene fluoride) membrane (PVDF-g-PAMPS) was prepared The influences of Na4SiO4 content, reaction temperature and time, content of ammonium persulfate and AMPS on PVDF-g-PAMPS membrane were discussed. The results show that the optimal reaction conditions are as follows: Na4SiO4 is 8%; ammonium persulfate is 0.016 mol / L; AMPS is 30 %; the reaction temperature is 80 °C and the reaction time is 1h. On the condition, PVDF-g-PAMPS membrane conductivity can reach to 1.27×10-2 S/cm.
Huaiying Zhou, Tianlong Gu, Daoguo Yang, Zhengyi Jiang, Jianmin Zeng
J. Xu et al., "Influencing Factors of Modified PVDF Grafted onto a Blended PAMPS(PVDF-G-PAMPS) Membrane", Advanced Materials Research, Vols. 197-198, pp. 1267-1270, 2011