Synthesis and Characterization of Binuclear Indium(Ⅲ) Complexes with Bis-Schiff Bases Derived from Benzidine or its Derivatives

Xu Dong Jin; Yue Hong Jin; Zhi Gang Cui; Yuan Yuan Li; Hai Bo Wang

doi:10.4028/www.scientific.net/AMR.197-198.627

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 197-198Synthesis and Characterization of Binuclear...

Synthesis and Characterization of Binuclear Indium(Ⅲ) Complexes with Bis-Schiff Bases Derived from Benzidine or its Derivatives

Abstract:

By reactions of indium chloride tetrahydrate with three bis-Schiff bases ligands (N, N’-bis (3-methoxy-salicylidene)benzidine = L¹; N, N’-bis (3-methoxysalicylidene)-2, 2’-dimethyl- benzidine =L²; N, N’-bis (3-methoxysalicylidene)-o- dianisidine = L³), respectively, three novel corresponding complexes 1~3 were obtained. The complexes were characterized by infrared spectrum, molar conductance, elemental analysis and thermal gravimetric analysis. The chemical formulae of the complexes 1~3 were determined as (InCl₃)₂Lⁿ (1, n = 1; 2, n = 2; 3, n = 3). All the complexes are constructed with binuclear indium ions. Every complex consists of two central In (III) ions, one corresponding bis-Schiff base ligand and six Cl^-.

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Advanced Materials Research (Volumes 197-198)

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627-630

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https://doi.org/10.4028/www.scientific.net/AMR.197-198.627

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February 2011

Authors:

Xu Dong Jin, Yue Hong Jin, Zhi Gang Cui, Yuan Yuan Li, Hai Bo Wang

Keywords:

Benzidine, Binuclear, Bis-Schiff Base, Indium Complex

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