Large scale of the industrial waste is not timely disposed of due to economic rapid development. It is the main reason why environmental pollution problem is getting more and more serious and we should monitor the pollution of industrial waste. A MODIS (Moderate Resolution Imaging Spectroradiometer) senor is used for long-time and dynamic environment monitor because it has advantages of high time resolution and high spectral resolution characteristics etc. SPOT satellite data is used to analyze the ground vegetation for its higher ground resolution and rich product data bases. The influence of industrial waste on environment is analyzed and the result of research is verifyed with the information of local meteorological agent and observation data of site. This method can be used for monitoring wide-range industrial waste and have good performance of monitoring and early warning industrial waste sites which are in mountainous area.