The Effect of POSS-NH2 on the Curing Reaction of Cyanate Ester Resin

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Abstract:

A functional POSS monomer (POSS-NH2) was employed to modify cyanate ester (CE) resin. A series of POSS-NH2/CE hybrids containing different content of POSS have been prepared by melt casting and then curing. The curing kinetics and reaction mechanisms of the resin systems were studied by using FT-IR. The experimental results show that both temperature and POSS content may influence the curing reaction of CE. POSS-NH2 mainly displays the catalytic effect at higher temperature (220oC). While the circumstance is more complex at lower temperature (190oC).

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Advanced Materials Research (Volumes 217-218)

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274-279

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March 2011

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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[1] I. Hamerton and J.N. Hay: Polymer. International Vol. 47 (1998), p.465.

Google Scholar

[2] W.K. Goertzen, M.R. Kessler. Composites: Part A Vol. 39 (2008), p.761.

Google Scholar

[3] P. Bartolomeo, J. Chailan, J. Vernet. European Polymer Journal, Vol. 37(2001), p.659.

Google Scholar

[4] S. A. Srinivasan, J.E. Mcgrath. Polymer Vol. 39 (1998), p.2415.

Google Scholar

[5] S.K. Karad, F.R. Jones, D. Attwood. Polymer Vol. 43 (2002), p.5643.

Google Scholar

[6] S.K. Karad, F.R. Jones, D. Attwood: Polymer Vol. 43 (2002), p.5643.

Google Scholar

[7] R. H. Baney, M. Itoh, A. Sakakibara, T. Suzuki. Chemical Review, Vol. 95(1995), p.1409.

Google Scholar

[8] G. Z. Li, L. C. Wang, H. L. Ni, C.U. Pittman Jr. Journal of Inorganic and Organometallic Polymers Vol. 11(2001), p.123.

Google Scholar

[9] T. Lu, G. Liang, Z. Guo, P. Ren, Z. Zhang: Chin. Polym. Bull. Vol. 2 (2004), p.15.

Google Scholar

[10] R.D. Miller: Science Vol. 286 (1999), p.421.

Google Scholar

[11] Z. Zhang, G. Liang, Tingli Lu: J. Appl. Polym. Sci. Vol. 103 (2007), p.2608.

Google Scholar

[12] Z. Zhang, G. Liang, P. Ren,J. Wang, J. Xie, X. Wang: Polym. Degrad. Stab. Vol. 92 (2007), p. (1986).

Google Scholar

[13] T. Lu, G. Liang, Z. Guo: J. Appl. Polym. Sci. Vol. 101 (2006), p.3652.

Google Scholar

[14] P. G. Ren, G. Z. Liang and Z. P. Zhang. Polym Compos Vol. 27 (2006), p.402.

Google Scholar

[15] S. C. Xu. Organic Chemistry, Higher Education Press, 2nd edition, p. (1991).

Google Scholar

[16] J. Bauer, M. Bauer. Microsystem Technologies Vol. 8 (2002), p.58.

Google Scholar

[17] J. Bauer, M. Bauer. Macromol. Chem. Phys. Vol. 202 (2001), p.2213.

Google Scholar