The Catalysis of 3, 8-Substituted Cobalt (II) Deuteroporphyrin Dimethyl Esters to the Oxidation of Cyclohexane by Air

Abstract:

A variety of 3, 8-substituted cobalt (II) deuteroporphyrin dimethyl esters were synthesized and used as catalysts in the oxidation of cyclohexane. The effect of substituents on catalytic activities of 3, 8-substituted cobalt (II) deuteroporphyrin dimethyl esters were investigated. The results showed that the catalytic activities were influenced by the electron effects and steric effects of substituents and the thermal stability of catalysts.

• Periodical: Advanced Materials Research (Volumes 233-235)
• Pages: 1093-1096
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.233-235.1093
• Online since: May 2011
• Authors: Shi Chao Xu, Bing Cheng Hu, Qiao Li Cui, Tian Jing Hu, Xiu You Huang, Zu Liang Liu
• Keywords: Air, Catalysis, Cyclohexane Oxidation, Deuteroporphyrins

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