Synthesis of Asymmetric Tridentate Cobalt(II) Complex and Application in Ethylene Oligomerization

Abstract:

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A kind of cobalt complex with asymmetric tridentate ligand was synthesized and used in ethylene oligomerization. The reaction temperature and Al/Co ratio had a great influence on the activities and distributions of the oligomer with methylaluminoxane as cocatalyst, and the main products were 1-butylene and hexene. A fast deactivation process was observed from the curve of the oligomerization kinetics.

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Edited by:

Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He

Pages:

1540-1543

DOI:

10.4028/www.scientific.net/AMR.233-235.1540

Citation:

C. G. Cao et al., "Synthesis of Asymmetric Tridentate Cobalt(II) Complex and Application in Ethylene Oligomerization", Advanced Materials Research, Vols. 233-235, pp. 1540-1543, 2011

Online since:

May 2011

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Price:

$35.00

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