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Synthesis of Asymmetric Tridentate Cobalt(II) Complex and Application in Ethylene Oligomerization
Abstract:
A kind of cobalt complex with asymmetric tridentate ligand was synthesized and used in ethylene oligomerization. The reaction temperature and Al/Co ratio had a great influence on the activities and distributions of the oligomer with methylaluminoxane as cocatalyst, and the main products were 1-butylene and hexene. A fast deactivation process was observed from the curve of the oligomerization kinetics.
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1540-1543
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May 2011
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© 2011 Trans Tech Publications Ltd. All Rights Reserved
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