Synthesis of Al-Containing Mesoporous Molecular Sieves and their Catalytic Performance to Isomerization Reaction of Endo-Tetrahydrodicyclo-Pentadiene

Sa Liu; Jian Wei Guo; Chu Fen Yang; Long Huan Li; Yi Hua Cui

doi:10.4028/www.scientific.net/AMR.233-235.234

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 233-235Synthesis of Al-Containing Mesoporous Molecular...

Synthesis of Al-Containing Mesoporous Molecular Sieves and their Catalytic Performance to Isomerization Reaction of Endo-Tetrahydrodicyclo-Pentadiene

Abstract:

Al-containing mesoporous molecular sieves(Al-MCM-41) were synthesized at ambient temperature. The structures of samples were characterized by XRD, N₂-adsorption/desorption isotherms and FT-IR, etc. The evaluation results showed that Al-MCM-41 had higher catalytic activity for isomerization conversion of endo-tetrahydrodicyclo-pentadiene (endo-TCD) into exo-tetrahydrodicyclo-pentadiene (exo-TCD) and adamantane (AdH). Loading inorganic acid on the surface of Al-MCM-41 led increase of its catalytic activity and the yield of adamantane.

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Advanced Materials Research (Volumes 233-235)

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234-237

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https://doi.org/10.4028/www.scientific.net/AMR.233-235.234

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Online since:

May 2011

Authors:

Sa Liu, Jian Wei Guo, Chu Fen Yang, Long Huan Li, Yi Hua Cui

Keywords:

Catalytic Isomerization, Mesoporous Molecular Sieve, Synthesis

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