Synthesis of Al-Containing Mesoporous Molecular Sieves and their Catalytic Performance to Isomerization Reaction of Endo-Tetrahydrodicyclo-Pentadiene

Abstract:

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Al-containing mesoporous molecular sieves(Al-MCM-41) were synthesized at ambient temperature. The structures of samples were characterized by XRD, N2-adsorption/desorption isotherms and FT-IR, etc. The evaluation results showed that Al-MCM-41 had higher catalytic activity for isomerization conversion of endo-tetrahydrodicyclo-pentadiene (endo-TCD) into exo-tetrahydrodicyclo-pentadiene (exo-TCD) and adamantane (AdH). Loading inorganic acid on the surface of Al-MCM-41 led increase of its catalytic activity and the yield of adamantane.

Info:

Periodical:

Advanced Materials Research (Volumes 233-235)

Edited by:

Zhong Cao, Lixian Sun, Xueqiang Cao, Yinghe He

Pages:

234-237

DOI:

10.4028/www.scientific.net/AMR.233-235.234

Citation:

S. Liu et al., "Synthesis of Al-Containing Mesoporous Molecular Sieves and their Catalytic Performance to Isomerization Reaction of Endo-Tetrahydrodicyclo-Pentadiene", Advanced Materials Research, Vols. 233-235, pp. 234-237, 2011

Online since:

May 2011

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Price:

$35.00

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