Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexes Containing 4,5-Diazafluorene Ligan

Jie Xiu Wang; Feng Zhao

doi:10.4028/www.scientific.net/AMR.239-242.2612

Paper Titles

Prediction of Tensile Modulus of 3D Four-Directional Braided Composites with Transverse Cracks
p.2590

UV-Vis/Ferrioxalate/H₂O₂ System on Degradation of Anthraquinone Dye Wastewater
p.2597

Transparent Aquabeads To Visualize Flow In Porous Material
p.2602

Preparation and Properties of Epoxy Matrix for Composite Cable Core
p.2606

Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexes Containing 4,5-Diazafluorene Ligan
p.2612

Synthesis of Aromatic Polyesters with Pendent Carboxyl Groups from Diphenolic Acid, Bisphenol a and Isophthaloyl Chloride by Interfacial Polycondensation
p.2616

A Dendronized Cellulose Derivative and its Thermotropic Liquid Crystal and Lyotropic Cholesteric Liquid Crystal Behaviors
p.2620

Preparation of NaA/PTFE Composite Membrane for Separation of DMF/H₂O Mixture by Pervaporation
p.2624

Low Temperature Method for Enhancing Ferroelectric Thin Films in Non-Volatile Random Access Memory Devices
p.2628

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 239-242Synthesis, Characterization and Photophysical...

Synthesis, Characterization and Photophysical Properties of Rhenium(I) Complexes Containing 4,5-Diazafluorene Ligan

Abstract:

Two related tricarbonyl rhenium complexes with the formula of [Re(CO)₃(L)Cl], where L=4,5-diazafluoren-9-one (Dafo-Re) and 9-(phenylamino)-4,5-diazafluoren (PADF-Re) were successfully synthesized with the aim to explore the effect of the geometry of Dafo on Rhenium(I) coordination, and characterized by ¹H NMR. Photophysical behaviors are investigated by UV–vis absorption and Fluorescence spectra. The two complexes Dafo-Re and PADF-Re show metal-to-ligand charge transfer absorptions at ca.391nm, ca.394 nm and emissions at ca.492nm, ca.470nm, respectively.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 239-242)

Pages:

2612-2615

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.239-242.2612

Citation:

Cite this paper

Online since:

May 2011

Authors:

Jie Xiu Wang, Feng Zhao

Keywords:

4.5-Diazafluoren-9-one, Characterization, Rhenium(I) Complex, Synthesis

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] (a) Stufkens. D. J, Antonin. Vlc ek. A. Jr, Coord. Chem. Rev. 177 (1998) 127. (b) Stufkens. D. J, Coord. Chem. Rev. 104 (1990) 39.

Google Scholar

[2] Kirgan. R, Simpson. M, Moore. C, Day. J, Bui. L, Tanner. C, Rillema. D. P, Inorganic Chemistry. 46 (2007) 6464.

DOI: 10.1021/ic700512j

Google Scholar

[3] S. Ranjan, S.-Y. Lin, K.C. Hwang, Y. Chi, W.-L. Ching, C.-S. Liu, Y.-T. Tao, C.-H.Chien, S.-M. Peng, G.-H. Lee, Inorg. Chem. 42 (2003) 1248.

Google Scholar

[4] Y. Li, Y. Liu, J. Guo, F.Wu, W. Tian, B. Li, Y.Wang, Synth. Met. 118 (2001) 175.

Google Scholar

[5] Gholamkhass. B, Mametsuka. H, Koike. K, Tanabe. T, Furue. M, Ishitani. O, Inorganic Chemistry. 44 (2005) 2326.

DOI: 10.1021/ic048779r

Google Scholar

[6] L.J. Henderson Jr., F.R. Fronczek, W.R. Cherry, J. Am. Chem. Soc. 106 (1984) 5876.

Google Scholar

[7] S. Menon, M.V. Rajasekharan, Polyhedron. 17 (1998) 2463.

Google Scholar

[8] E. Runge, E.K.U. Gross, Phys. Rev. Lett. 52 (1984) 997.

Google Scholar

[9] S.L. Mayo, B.D. Olafso, W.A. Goddard, J. Phys. Chem. 94 (1990) 8897.

Google Scholar

[10] Zhang. L, Li. B, Inorganica Chimica Acta. 362 (2009) 4857.

Google Scholar

[11] Yam. V. W.-W, Yang. Y, Zhang. J, Chu. B. W.-K, Zhu. N, Organometallics. 20 (2001) 4911.

Google Scholar

[12] Yam. V. W.-W, Lau. V. C.-Y, Wu, L.-X, J. Chem. Soc., Dalton Trans. (1998) 1461.

Google Scholar

[13] S. Ranjan, S.-Y. Lin, K.C. Hwang, Y. Chi, W.-L. Ching, C.-S. Liu, Y.-T. Tao, C.-H.Chien, S.-M. Peng, G.-H. Lee, Inorg. Chem. 42 (2003) 1248.

Google Scholar

[14] Guerrero. J, Piro. O. E, Wolkan.E, Feliz. M.R, Ferraudi. G,Moya. S. A., Organometallics. 20 (2001) 2842.

Google Scholar