Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity

Bo Xiao; Qian Qian Li; Li Jun Yang; Shao Ming Fang

doi:10.4028/www.scientific.net/AMR.239-242.2683

Paper Titles

Effect of Drying Methods on Structure and Mechanical Properties of Bacterial Cellulose Films
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Preparation of Sn⁴⁺ -Doped TiO₂ and Investigation of its Photocatalytic Activity
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Micron Sized Polyurethane Shape-Memory Polymer Beads
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Effect of Interconnectivity of Nickel on Electrical and Thermal Properties of Alumina-Ni Interpenetrating Phase Composite
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Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity
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Silane Treatment Technology on Aluminum Surface
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Analysis of Numerical Simulation in the Deep Drawing of Box-Shaped Parts Using Variable Blank Holder Force
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A Study of N Heterocyclic Compound as a Potential Lubricating Oil Additive
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Research on Temperature Field Distribution of Heavy Hydrostatic Thrust Bearing Rotation-Workbench at Different Rotating Velocity
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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 239-242Rational Construction of Polymeric Mercuric(II)...

Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity

Abstract:

New 1-D zigzag chain coordination polymer {[HgBr₂(pbbm)]^.DMF}_n (1) has been successfully constructed with the aim of exploiting new and potent ion-exchange materials. Remarkably, the coordinated Br^- anions in the title polymer can be replaced completely by F^-, Cl^- and I^- anions when the crystals are immersed in the aqueous solutions of the corresponding potassium salts, respectively. This exchange is quantified by FT-IR spectra, the PXRD pattern as well as EDS analyses.