Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity

Abstract:

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New 1-D zigzag chain coordination polymer {[HgBr2(pbbm)].DMF}n (1) has been successfully constructed with the aim of exploiting new and potent ion-exchange materials. Remarkably, the coordinated Br- anions in the title polymer can be replaced completely by F-, Cl- and I- anions when the crystals are immersed in the aqueous solutions of the corresponding potassium salts, respectively. This exchange is quantified by FT-IR spectra, the PXRD pattern as well as EDS analyses.

Info:

Periodical:

Advanced Materials Research (Volumes 239-242)

Edited by:

Zhong Cao, Xueqiang Cao, Lixian Sun, Yinghe He

Pages:

2683-2686

DOI:

10.4028/www.scientific.net/AMR.239-242.2683

Citation:

B. Xiao et al., "Rational Construction of Polymeric Mercuric(II) Imidazole with High Anion Exchange Capacity", Advanced Materials Research, Vols. 239-242, pp. 2683-2686, 2011

Online since:

May 2011

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Price:

$35.00

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