Bonding Force Investigation between C-S-H Clusters in the C3S Pastes and AFM Tip

Article Preview

Abstract:

With the experimental objects of the C3S pastes curing at 60 days with water-solid ratio of 0.5, the micro mechanical characteristic between C-S-H clusters and tip has been investigated in the low scale. The results show that the experimental method is feasible for bonding force between C-S-H clusters and tip using atomic force microscopy (AFM) in the real atmospheric conditions. Though bonding force values are discrete in view of the anisotropy character of the cement-based material, the normal distribution can be fitted for the variation of bonding force between C-S-H blusters in the C3S pastes and AFM tip with a mean of 6.2nN. Even if bonding force values is somewhat higher due to the roughness and the measuring conditions in the paper, the experimental method using AFM could still be effective for the lateral correlation for bonding force of the different systems. The research on bonding force between C-S-H clusters would play the important role in establishing the new microscopic structural model.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 250-253)

Pages:

630-635

Citation:

Online since:

May 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Y. Nanru: C-S-H gel and its determination methods, Bulletin of the Chinese Ceramic Society. 2 (2003), pp.46-52.

Google Scholar

[2] H. F. W. Taylor: Cement chemistry, Academic Press, New York(1990).

Google Scholar

[3] A. Nonat, J. C. Mutin: From hydration to setting, Proceedings of the International RILEM Worshop, E&FN SPON, London(1991).

Google Scholar

[4] B. Chunli, T. Fang, L. Ke: Scanning force microscopy, Science Press, Beijing(2000).

Google Scholar

[5] E. Finot, E. Lesniewska: Reactivity of gypsum faces according to the relative humidity by scanning force microscopy, Surface Science, 384(1997), pp.201-217.

DOI: 10.1016/s0039-6028(97)00220-3

Google Scholar

[6] S. Lesko, E. Lesniewska, Investigation by atomic force microscopy of forces at the origin of cement cohesion, Ultramicroscopy, 86 (2001), pp.11-21.

DOI: 10.1016/s0304-3991(00)00091-7

Google Scholar

[7] C. Plassard, E. Lesniewska: Nanoscale experimental investigation of particle interactions at the origin of the cohesion of cement, Langmuir, 21 (2005), pp.7263-7270.

DOI: 10.1021/la050440+

Google Scholar

[8] P. Mondal, S. P. Shah, and L. D. Marks: Nanoscale characterization of cementitious materials, ACI Materials Journal, March-April(2008), pp.174-180.

Google Scholar

[9] A. Nonat: The structure and stoichiometry of C-S-H, Cement and Concrete Research, 34(2004), pp.1521-1528.

Google Scholar

[10] H. M. Jennings: A model for the microstructure of calcium silicate hydrate in cement paste, Cement and Concrete Research, 30(2000), pp.101-116.

DOI: 10.1016/s0008-8846(99)00209-4

Google Scholar

[11] B. Chunli, T. Fang: The Scanning Force Microscope, Modern Scientific Instrument, 1(1998), pp.79-83.

Google Scholar

[12] Z. Peinan: Microstructure atlas of the inorganic nonmetallic materials, Publishing Company of Wuhan Industrial University, Wuhan(1994).

Google Scholar

[13] L. Longquan, Z. Yurui, J. Gu: Quantitative Chemical Analysis, Publishing House of Science and Technology University, Beijing(2005).

Google Scholar

[14] G. Liqiu, L. Ji: Reduction of long-range force interaction using AFM carbon nanotube tip, Chinese Journal of Mechanical Engineering, Vol. 40 N.10 (2004), pp.15-18.

DOI: 10.3901/jme.2004.10.015

Google Scholar

[15] M. Kostoglou, A. J. Karabelas: Effect of roughness on energy of repulsion between colloidal surfaces, Journal of Colloid and Interface Science, 171(1995), pp.187-199.

DOI: 10.1006/jcis.1995.1166

Google Scholar

[16] M. C. Herman, K. D. Papadopoulos: A method for modeling the interactions of parallel flat plates systems with surface feature, Journal of Colloid and Interface Science, 142(1991), pp.331-342.

DOI: 10.1016/0021-9797(91)90064-f

Google Scholar

[17] D. Atkins, P. Ke kicheff, O. Spalla: Adhesion between colloidal silica as seen with direct force measurement, Journal of Colloid and Interface Science, 188 (1997), pp.234-237.

DOI: 10.1006/jcis.1996.4751

Google Scholar

[18] R. J.-M. Pellenq, N. Lequeux, H. van Damme: Engineering the bonding scheme in C–S-H: The iono-covalent framework, Cement and Concrete Research, 38 (2008), pp.159-174.

DOI: 10.1016/j.cemconres.2007.09.026

Google Scholar

[19] G.Toikka, R. A. Hayes, J. Ralston: Langmuir, 12 (1996), pp.3783-3788.

Google Scholar