Synthesis of Carbazoled Poly(Arylene Imino)

Abstract:

Article Preview

The carbazoled poly(arylene imino)s (c-PAI) have been synthesized via palladium-catalyzed polycondensation of 3,6-diamino-N-(2-ethylhexyl)carbazole with different aromatic dibromides. The structure of c-PAI were characterized by means of FT-IR, 1H NMR spectroscopy and elemental analysis, the results show an agreement with the proposed structure. The thermal properties of c-PAI were detected by DSC and TG. The result show that the polymers possess high glass transition temperature (Tg>250°C ), good thermal stability with high decomposition temperatures (TD>410°C), In addition to the thermal properties, the optical properties were studied, including Uv-vis absorption, photoluminescence and time of flight (TOF).

Info:

Periodical:

Advanced Materials Research (Volumes 284-286)

Main Theme:

Edited by:

Xiaoming Sang, Pengcheng Wang, Liqun Ai, Yungang Li and Jinglong Bu

Pages:

1863-1866

DOI:

10.4028/www.scientific.net/AMR.284-286.1863

Citation:

W. W. Shan et al., "Synthesis of Carbazoled Poly(Arylene Imino)", Advanced Materials Research, Vols. 284-286, pp. 1863-1866, 2011

Online since:

July 2011

Export:

Price:

$35.00

In order to see related information, you need to Login.

In order to see related information, you need to Login.