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Synthesis and Characterization of Tri-N-Octylamine-Intercalated α-Zirconium Phosphate
Abstract:
Tri-n-octylamine-intercalated α-zirconium phosphate (TOA-ZrP) was prepared in the presence of (C4H9)4NOH for the first time. The interlayer distance of (C4H9)4NOH-intercalatedα-zirconium phosphate (B-ZrP) is 14.7 Å, larger than that ofα-ZrP (7.6 Å). The TOA-ZrP sample is highly crystallized with the interlayer distance of 22.3 Å. The molar ratio of TOA toα-ZrP in the intercalation composite was found to be 1/1.21. The composite can find application in solid extraction.
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234-237
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July 2011
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© 2011 Trans Tech Publications Ltd. All Rights Reserved
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