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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 287-290Solvent Extraction and Separation of Palladium(II)...

Solvent Extraction and Separation of Palladium(II) from Hydrochloric Acid Medium with N-Benzothiazolylazo Butyl Imide

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Abstract:

A new extractant,N-benzothiazolylazo Butyl Imide(BBI),was synthesized and identified by elemental analysis,infrared spectrum and nuclear magnetic resonance (NMR).The extraction of Pd(II) using BBI diluted with CHCl₃ show high efficiency in 0-0.4M HCl medium.The dependence of the extraction percentages of Pd(II),Pt(IV)and base metal ions (Fe(III),Cu(II),and Zn(II)) on the HCl and BBI concentrations demonstrate that the idea condition for Pd(II) extraction is 0-0.4M HCl, 0.01-0.05M BBI.The stoichiometric ratio of Pd(II)-BBI complex is 1:2.The loading capacity of Pd(II) is about 0.5g/L using 0.1M BBI,which is comparable to that using DBSO.Complete stripping of Pd(II),Pt(IV) from loaded organic was proposed with 0.5M thiourea and 0.1M HCl.The Pd(II)-BBI-Cl complex has been characterized by elemental analysis,IR and ¹HNMR spectra.

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Periodical:

Advanced Materials Research (Volumes 287-290)

Pages:

1626-1631

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.287-290.1626

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Online since:

July 2011

Authors:

Li Li Chen, Zu Min Qiu, Juan Huang

Keywords:

N-Benzothiazolylazo Butyl Imide, Palladium, Solvent Extraction

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© 2011 Trans Tech Publications Ltd. All Rights Reserved

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