Synthesis and Characterization of Rodlike Ammonium Tetrathiomolybdate and its Thermal Decomposition Mechanism

Jun Zhang; Su Ping Hu; Yu Li Feng; Bo Xu; Yan Hui Guo

doi:10.4028/www.scientific.net/AMR.287-290.2049

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 287-290Synthesis and Characterization of Rodlike Ammonium...

Synthesis and Characterization of Rodlike Ammonium Tetrathiomolybdate and its Thermal Decomposition Mechanism

Abstract:

Rodlike ammonium tetrathiomolybdate has been synthesized via ultrasonic assistance using monocrystal ammonium dimolybdate and ammonium sulfide as raw materials. The phase compositions, purity of as-synthesized products were characterized by x-ray diffraction (XRD), Fourier transform infrared spectroscopy (FT-IR), laser Raman spectroscopy(LRS). The thermal decomposition mechanism of ammonium tetrathiomolybdate was deduced by thermoanalysis. It is shown that brownish-red rhombic ammonium tetrathiomolybdate crystal with high purity could be obtained at 60°C for 1h under relatively mild conditions.

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Advanced Materials Research (Volumes 287-290)

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2049-2052

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.287-290.2049

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Online since:

July 2011

Authors:

Jun Zhang, Su Ping Hu, Yu Li Feng, Bo Xu, Yan Hui Guo

Keywords:

Ammonium Tetrathiomolybdate, Sonochemical Synthesizing, Thermal Decomposition

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References

[1] H. W. Wang, P. Skeldon, G. E. Thompson: J.Mater. Sci. Lett. Vol 15(1996), pp.494-496

Google Scholar

[2] P. Richard, S.Harold: Catal. Today. Vol 31(1996), pp.65-67

Google Scholar

[3] R. Poulomi, K.S. Suneel: Thin Solid Films. Vol 496(2006), pp.293-298

Google Scholar

[4] A. Miller, E. Diemann: Transition metal chemistry current problems of general, biological and catalytical relevances[M].Weinheim: Verlag Chemie. 1981.

Google Scholar

[5] T. A. Pecoraro, R. R.Chianelli: US Patent: 4528089, 1985.

Google Scholar

[6] A.J. Jacobson, R. R. Chianelli, T.A. Pecoraro: US Patent, 4650563, 1987.

Google Scholar

[7] G. Alonso, G. Berhault, A. Aguilar: Coal Liquefaction and Catal. Vol 208(2002), pp.359-369.

Google Scholar

[8] Dapeng Liu, Ruiyu Zhao, Yongming Chai. Acta Petrolei Sinica (Chin.), Vol 20(6)(2004),pp.28-31.

Google Scholar

[9] Chenguang Liu, Yongming Chai, HuijiZhao. China Patent: 200410039454.6, (2004)

Google Scholar

[10] P.Afanasiev, G. F. Xia, G. Berhoult, Mater. Chem. Vol 11(11) (1999), pp.3216-3219.

Google Scholar

[11] J.H. Zhang, Z.D. Zhang, X.F. Qian. J. Solid State Chem. Vol 141(1)(1998), pp.270-273.

Google Scholar

[12] Yongqiang Zhang, Xihong Chen. Inorg. Chem. Ind.(Chin.). Vol 37(12) (2005), pp.20-21.

Google Scholar

[13] Yongming Chai, Huiji Zhao,Yunqi Liu. Inorg. Chem. Ind. (Chin.). Vol 39(5)(2007), pp.12-15.

Google Scholar