Study on Crystallization Characteristic of 3PE Anti-Corrosion Coating for Steel Pipeline

Article Preview

Abstract:

Three layers polyethylene (3PE) anti-corrosion coating was widely used in oil or gas transmission pipelines in the world. Special HDPE (SHDPE) was used in the outer layer of 3PE coating, which is very important to the performance of the whole coating system. However, till to now fewer study about SHDPE crystallization have been reported. In this paper, the crystallization characteristic of SHDPE and 3PE coating were investigated by differential scanning calorimetry (DSC), wide-angle X-ray diffraction (WAXD), modulated differential scanning calorimetry (MDSC). The results showed that, the crystallinity and lamella thickness of SHDPE were decreased with the increase of cooling rate in fabrication process. Middle adhesion layer of 3PE coating accelerated nucleation and improved the crystallinity of the near zone PE layer. The skin region of 3PE coating had lowest crystallinity due to the highest cooling rate, and the crystallinity was increased from skin to core region of 3PE coating.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 287-290)

Pages:

2169-2174

Citation:

Online since:

July 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Marcel Roche, Denis Melot, G. Paugam, Recent experience with pipeline coating failures, 16th International Conference on Pipeline Protection, BHR Group, Paphos, Cyprus, 11, 2005: 2-4

Google Scholar

[2] T. Kamimura and H. Kishikawa, Mechanism of cathodic disbonding of three-layer polyethylene-coated steel pipe,Corrosion 54(21)1998:979-987

DOI: 10.5006/1.3284820

Google Scholar

[3] C. Zhong, X. Tang, Y.F. Cheng, Corrosion of steel under the defected coating studied by localized electrochemical impedance spectroscopy, Electrochimica Acta, 53, 2008: 4740–4747

DOI: 10.1016/j.electacta.2008.02.014

Google Scholar

[4] Jie Kong, Xiaodong Fan, Wenqiang Qiao, Study of a skin-core type of crystallinity distribution within polyethylene specimen crystallized under high pressure, Polymer, 2005 (46): 7644-7651

DOI: 10.1016/j.polymer.2005.04.108

Google Scholar

[5] Callon N K, spencer M, Crawfard R J .Effects of cooling rate on the mechanical properties of rotationally moulded polyethylene parts, ANTEC Papers, (2002)

Google Scholar

[6] Gonnet J.M, Guillet J., Sirakov J., "In-situ"Monitoring of the non-isothermal crystallization of polymers by dielectric spectroscopy, Polymer Engineering and Science, 2002, 42 (6) : 1159-1170.

DOI: 10.1002/pen.11020

Google Scholar

[7] Sperling L.H., Introduction to physical polymer science, 2nd ed, New York: Wiley, 1992:198

Google Scholar

[8] Bassett DC. Principles of polymer morphology. London, UK: Cambridge University Press; 1981.

Google Scholar

[9] Meo O. Ngui, Surya K. Mallapragada, Quantitative analysis of crystallization and skin formation during isothermal solvent removal from semicrystalline polymers, Polymer, 1999 (40): 5393-5400

DOI: 10.1016/s0032-3861(98)00737-x

Google Scholar

[10] L. Quintanilla, J.C. Rodríguez-Cabello, T. Jawhari, Structural analysis of injection-moulded semicrystalline polymers by Fourier transform infra-red spectroscopy with photoacoustic detection and differential scanning calorimetry: 1. Poly(ethylene terephthalate) , Polymer, 1993 (34): 3787-3795

DOI: 10.1016/0032-3861(93)90502-2

Google Scholar

[11] Reading M., Elliott D., Hill V.L., New approach to the calorimetric investigation of physical and chemical transitions, Journal of thermal analysis, 1993, 40: 949–955

DOI: 10.1007/bf02546854

Google Scholar

[12] Gill PS, Sauerbrern SR, Reading M., Modulated differential scanning calorimetry, Journal of thermal analysis, 1993, 40: 931–939

DOI: 10.1007/bf02546852

Google Scholar