Synthesis and Liquid Crystal Properties of a New Organometallic Palladium Complex

Jian Qiang Liu; Xing Qi Fu; Jian Ye Song; Yun Xu Fu; Xing Cheng Zhang; Wan Guo Hou

doi:10.4028/www.scientific.net/AMR.306-307.242

Paper Titles

Synthesis, Crystal Structure and Photoluminescence of Eu(Phen)(DMF)₂(NO₃)₃ (Phen = Phenanthroline and DMF = N,N-Dimethylformamide)
p.224

Synthesis, Characterization and Luminescence of Europium, Terbium Complexes of 1,1'-(Pyridin-2,6-Diyl) Bis-3-P-Tolylpropane-1,3-Dione
p.228

Comparison between Vanadium Dioxides Produced by Ammonium Metavanadate and Vanadium Pentoxide
p.234

Electron Stimulated Surface Chemical Reaction Mechanism for Phosphor Degradation
p.238

Synthesis and Liquid Crystal Properties of a New Organometallic Palladium Complex
p.242

Growth of p-Type AlN Crystals by C and Si Codoping
p.246

Promising Zn₃Ta₂O₈:Pr³⁺ Red Phosphor for Low Voltage Cathodoluminescence Applications
p.251

Optical Properties of the 3-D Composite Photonic Crystals Prepared by Modified Dip-Coating and Coating First Method
p.255

Synthesis and Properties of Poly(3,4-Ethylenedioxythiophene) via Solid-State Polymerization
p.261

HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 306-307Synthesis and Liquid Crystal Properties of a New...

Synthesis and Liquid Crystal Properties of a New Organometallic Palladium Complex

Abstract:

A new organometallic palladium coordinated liquid crystal that was written by PdS6 had been synthesized by chelating reaction of the tetrachloropalladate (PdCl₄^2-) and the star-like liquid crystal (S6) containing four hexyloxyazobenzene mesogens in its periphery. The structure and liquid crystallinity (LC) of PdS6 were characterized by infrared absorption spectroscopy (IR), ultraviolet absorption spectra (UV), nuclear magnetic resonance spectroscopy (NMR), elemental analysis (EA), polarizing optical microscope (POM), X-ray diffraction (XRD) and differential scanning calorimetry (DSC). The phase behavior of PdS6 was Cr155N230I205N160Cr, its melting point and clearing temperature were higher than those of the free azo ligand S6, its mesophase range wass broader than S6’s. It will be used as a new type photoelectric functional material in the future.

You might also be interested in these eBooks

View Preview

Info:

Periodical:

Advanced Materials Research (Volumes 306-307)

Pages:

242-245

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.306-307.242

Citation:

Cite this paper

Online since:

August 2011

Authors:

Jian Qiang Liu, Xing Qi Fu, Jian Ye Song, Yun Xu Fu, Xing Cheng Zhang, Wan Guo Hou

Keywords:

Complex, Liquid Crystal, Organometallic, Palladium, Phase Behaviour, Photoelectric Material

Export:

RIS, BibTeX

Price:

Permissions CCC:

Request Permissions

Permissions PLS:

Request Permissions

Сopyright:

Citation:

References

[1] C. K. Lee, H. H. Peng and I. J. B. Lin: Chem. Mater. Vol.16 (2004), p.530.

Google Scholar

[2] M.C. Torralba, M. Cano, J.A. Campo, J.V. Heras, E. Pinilla and M.R. Torres: Inorg. Chem. Comm. Vol.9 (2006), p.1271.

Google Scholar

[3] W. Y. Wong and C. L. Ho: Coord. Chem. Rev. Vol.253 (2009), p.1709.

Google Scholar

[4] M.J. Baena, J. Buey, P. Espinet and C.E. García-Prieto: J. Organomet. Chem. Vol.690 (2005), p.998.

Google Scholar

[5] D. Astruc, C. Ornelas and J. R. Aranzaes: J. Inorg. Organomet. Polym. Vol.18 (2008), p.4.

Google Scholar

[6] O. N. Kadkin, E. H. Kim, S. Y. Kim and M. G. Choi: Polyhedron Vol.28 (2009), p.1301.

Google Scholar

[7] M. Ghedini, M. Longeri and R. Bartolino: Mol. Cryst. Liq. Cryst. Vol.84 (1982), p.207.

Google Scholar

[8] R. J. Twieg, V. Chu, C. Nguyen, C. M. Dannels and C. Viney: Liq. Cryst. Vol. 20 (1996), p.287.

Google Scholar

[9] G. W. Gray and J. W. G. Goodby: Smetic Liquid Crystals (Leonard Hill, Glasgow and London, 1984).

Google Scholar

[10] A. De Vries: Mol. Cryst. Liq. Cryst. Vol.131 (1985), p.125.

Google Scholar

[11] K. L. Wooley, C. J. Hawker, J. M. Pochan and J. M. J. Fréchet: Macromolecules Vol.26 (1993), p.1514.

Google Scholar

[12] K. Lorenz, D. Hölter, B. Stühn and H. Frey: Adv. Mater. Vol.8 (1996), p.414.

Google Scholar

[13] K. Merkel, A. Kocot, J. K. Vij, G. H. Mehl andT. Meyer: J. Chem. Phys. Vol.121 (2004), p.5012.

Google Scholar

[14] W. H. de Jeu and W. A. P. Claassen: J. Chem. Phys.Vol. 67 (1977), p.3705.

Google Scholar

[15] J. W. van Dijk and W. H. de Jeu: J. Chem. Phys. Vol.79 (1983), p.3888.

Google Scholar