TEM and DSC Studies on the Synthetic Diamond Grown from Fe-Ni-C-B System under HPHT

Article Preview

Abstract:

Transmission Electron Microscope (TEM) and Different Scanning Calorimetry (DSC) Methods Were Used to Investigate the Diamonds Grown with Different Boron Content Alloy Catalysts under High-Pressure High-Temperature (HPHT). Experimental Results Demonstrated the Microstructure and Composition of Boride Compounds in Synthetic Diamond, such as (FeNi)23(CB)6 ,(Fe, Ni)3(C,B), (Fe,Ni)B and B4C, Whose Formation Process Was Analyzed. the Thermal Stability of Diamond Depends on Boron Concentration in Catalyst According to DSC Studies. we Analyzed the Reason of Diamond Oxidation.The Work Offers Valuable Information for Improving the Thermal Stability of Synthetic Diamond Crystals by Adjusting Boron Content in the Fe-Ni Based Catalyst.

You might also be interested in these eBooks

Info:

Periodical:

Pages:

3-7

Citation:

Online since:

August 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Li, Shang-Shen; Ma, Hong-An and Li, Xiao-Lei. Synthesis and characterization of p-type boron-doped IIb diamond large single crystals, Chinese Physics B, 20 (2011).

DOI: 10.1088/1674-1056/20/2/028103

Google Scholar

[2] Shah ZM, Mainwood A. A theoretical study of the effect of nitrogen, boron and phosphorus impurities on the growth and morphology of diamond surfaces, Diamond and related materials, 17(7-10) (2008) pp.1307-1310.

DOI: 10.1016/j.diamond.2008.03.028

Google Scholar

[3] Long, Run, Dai, Ying, Guo, Meng. Effect of B-complexes on lattice structure and electronic properties in heavily boron-doped diamond, Diamond and Related Materials, v17, (2008) pp.234-239.

DOI: 10.1016/j.diamond.2007.12.019

Google Scholar

[4] Dai, Ying, Long, Run, Huang, Baibiao. Effect of boron on the superconducting transition of heavily doped diamond, Diamond and Related Materials, 16 (2007) pp.353-358.

DOI: 10.1016/j.diamond.2006.07.004

Google Scholar

[5] Li, H. S, Qi, Y.X., Gong, J.H. High-pressure synthesis and characterization of thermal-stable boron-doped diamond single crystals, International Journal of Refractory Metals and Hard Materials, 27 (2009) pp.564-570.

DOI: 10.1016/j.ijrmhm.2008.07.015

Google Scholar

[6] Liangq, Qi, Catledqe, Shane A., Vohra, Mechanical properties of boron doped diamond films prepared by MPCVD, Materials Research Society Symposium - Proceedings, Mechanical Properties of Nanostructured Materials and Nonocomposites, v 791 (2003).

DOI: 10.1557/proc-791-q8.19

Google Scholar

[7] Barnes, R. Bangert, U. Martineau, P. HR-TEM imaging and image simulation of vacancy clusters in brown diamond. Physica Status Solidi (A) Applications and Materials, 203, 12 (2006) pp.3081-3087.

DOI: 10.1002/pssa.200671111

Google Scholar

[8] Langenhorst, F. Poirier, J. -P. Frost, D.J. TEM observations of microscopic inclusions in synthetic diamond, Journal of Materials Science, 39, 5 (2004)pp.1865-1867.

DOI: 10.1023/b:jmsc.0000016205.14981.11

Google Scholar

[9] L. -W. Yin, Z. -D. Zou and M. -S. Li, Impurities identification in a synthetic diamond by transmission electron microscopy, Diamond and Related Materials, 9, 12(2000) 2006-(2009).

DOI: 10.1016/s0925-9635(00)00355-1

Google Scholar

[10] Pavel, E.; Baluta, Gh.; Barb, D., Nature of the metrallic inclusions in syntetic diamond crystals synthesized at approximately 5. 5 Gpa in Fe-C system, Solid State Communications, Vol76, (1990) pp.531-533.

DOI: 10.1016/0038-1098(90)90664-w

Google Scholar

[11] Pavel, E.; Baluta, Gh.; Barb, D., (Fe1-XMex)3C carbide identification in synthetic diamond crystals produced at high pressure and high temperature in Fe-Me-C systems, where Me=Ni, Co, Materials Letters, 10, (1990) pp.62-65.

DOI: 10.1016/0167-577x(90)90015-e

Google Scholar

[12] L.W. Yin, Z. D Zou and M.S. Li., Some inclusions and defects in a synthetic diamond single crystal, Journal of Crystal Growth, Vol218, (2000) 455-458.

DOI: 10.1016/s0022-0248(00)00562-5

Google Scholar

[13] Y.A. Kocherzhinskii, O.G. Kulik, V.Z. Turkevich, High Temp. -High Press. Vol 25, (1993) p.113.

Google Scholar

[14] Hsu, B. -L. Prelas, M.A. Ghosh, T.K. Diffusion of boron in single-crystal diamond (Type IIa) using field enhanced diffusion Transactions of the American Nuclear Society, Vol 85, (2001) p.505.

Google Scholar

[15] Yu.V. Turov, B.M. Khusid and L.G. Voroshnin, Structure formation under sintering of powder iron-boron carbide composite, Poroshkovaya Metallurgiya, Vol 6, (1991) pp.25-31.

DOI: 10.1007/bf00795069

Google Scholar

[16] J. J. Suñol, A. González and J. Saurina, Thermal and structural characterization of Fe–Nb–B alloys prepared by mechanical alloying  Materials Science and Engineering A, 375-377, 15 (2004) pp.874-880.

DOI: 10.1016/j.msea.2003.10.194

Google Scholar

[17] V.P. Poliakov, A.A. Ermolaev and A.I. Laptev, The influence of boron compounds' particles (TiB2, BNcub) on the thermal stability and the mechanical strength of synthesized carbonado after heating, Diamond and Related Materials, Vol 10, 11 (2001).

DOI: 10.1016/s0925-9635(01)00478-2

Google Scholar