Synthesis, Structural Characterization and Luminescence Property of Ring-Like Zinc(II) Complex of N-Paratoluensulfonyl-Glycine Acid and 1,10-Phenanthroline
A novel ring-like zinc (II) complex of N-paratoluensulfonyl-glycine acid and 1,10-phenanthroline was synthesized and characterized by elemental analysis, IR spectrum and molar conductivity. The crystal structure of Zn (II) was determined by X-ray single crystal diffraction. The results show that each zinc (II) atoms is in a distorted trigonal bipyramidal geometry and form 16-membered chelate ring with the tridentate ligand. Intermolecular weak interactions in complex link molecules into a one-dimensional infinite chain supramolecular structure. The luminescence property of the complex was investigated in solid.
Helen Zhang and David Jin
X. S. Tai "Synthesis, Structural Characterization and Luminescence Property of Ring-Like Zinc(II) Complex of N-Paratoluensulfonyl-Glycine Acid and 1,10-Phenanthroline", Advanced Materials Research, Vol. 321, pp. 127-130, 2011