The Analysis of Dynamic Viscoelastic Properties of Regenerated Cellulose at Different Temperature and Humidity

Article Preview

Abstract:

The effects of temperature and relative humidity on regenerated cellulose had been investigated in detail in the present work. From experimental results, it was shown that with increasing of RH within temperature range of 35~65°C, storage modulus Er decreased, loss tangent tanδ increased. This indicated that water molecules penetrate into cellulose and mask off inter- and intra-chain hydrogen bonds and make some motion units to move. More importantly, experimental results indicated that three regenerated cellulose samples had different microstructure and superstructure, which greatly affects the properties of regenerated cellulose. So it will be very valuable to further study the effect.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 335-336)

Pages:

869-872

Citation:

Online since:

September 2011

Authors:

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2011 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] N. A, El-Wakil, M. L.Hassan. Structural changes of regenerated cellulose dissolved in FeTNa, NaOH/thiourea, and NMMO systems. Journal of Applied Polymer Science, Vol.109, No.5(2008), pp.2862-2871..

DOI: 10.1002/app.28351

Google Scholar

[2] W. Gindl, K. J. Martinschitz. Orientation of cellulose crystallites in regenerated cellulose fibres under tensile and bending loads. Cellulose, Vol.13, No.6(2006), pp.621-627.

DOI: 10.1007/s10570-006-9074-z

Google Scholar

[3] S. M. Zhou, K. Tashiro, T. Hongo. Influence of water on structure and mechanical properties of regenerated cellulose studied by an organized combination of infrared spectra, X-ray diffraction, and dynamic viscoelastic data measured as functions of temperature and humidity. Macromolecules, Vol.34, No.5(2001), pp.1274-1280.

DOI: 10.1021/ma001507x

Google Scholar

[4] M. Inamoto. Morphological formation of the regenerated cellulose membranes recovered from its cuprammonium solution using various coagulants. Polymer. J., Vol.28(1996), pp.507-512.

DOI: 10.1295/polymj.28.507

Google Scholar

[5] T. Hongo. Super-molecular structures containing the swelling behavior of regenerated cellulose membranes. Polym. J., Vol.28(1996), pp.769-779.

DOI: 10.1295/polymj.28.769

Google Scholar