The Preparation Conditions of Catalyst for Steam Reforming of Fast Pyrolysis Bio-Oil

Abstract:

Catalytic steam reforming of bio-oil is an economically feasible route producing renewable hydrogen. Ni/MgO-La2O3-Al2O3 catalyst was prepared with Ni as active agent, Al2O3 as support and MgO, La2O3 as promoters. The experiments were carried out in a fixed-bed reactor. The content of Ni, calcination temperature, and calcinations time, were investigated with hydrogen yield as index. The optimal preparation conditions were concluded as follows: the Ni content 18%, the calcination temperature 8500C and the calcinations time 6 h.

• Periodical: Advanced Materials Research (Volumes 347-353)
• Pages: 2231-2235
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.347-353.2231
• Online since: October 2011
• Authors: Ping Lan, Li Hong Lan, Tao Xie, An Ping Liao
• Keywords: Bio-Oil, Catalyst, Catalytic Steam Reforming, Preparation Conditions

References

[1] Pena M.A., Gomez J.P., Fierro J.L.G. . Appl. Catal. A, 144:7-57(1996).

[2] Marquevich M., Sonneman G.W., Castells F., et al. Green Chem. 4: 414-423(2002).

[3] Effendi A., Zhang Z.G., Hellgardt K. , et al. Catal .Today, 77:181-189(2002).

[4] Garcia L., Salvador M.L., Arauzo J., et al. Energy & Fuels, 13:851-859(1999).

[5] Basagiannis A.C. Verykios X.E. . Appl. Catal. A,308:182-93(2006).

[6] Wang D., Montane D. Chornet E.. Appl. Catal. A, 143:245-270(1996).

[7] Garcia L., French R., Czernik S., et al. Appl. Catal. A, 201:225-239(2000).

[8] Delgado J., Aznar M.P., Corella J.. Ind. Eng. Chem. Res., 1996, 35(10), 3637-3643.

[9] Delgado J., Aznar M.P.. Ind. Eng. Chem. Res., 1997, 36(5), 1535-1543.

[10] Olivares A., Aznar M.P., Caballero M.A., et al. Ind. Eng. Chem. Res., 1997, 36(12), 5220-5226.

[11] Narváez I., Orío A., Aznar M.P., et al. Ind. Eng. Chem. Res., 1996, 35(7), 2110-2120.

[12] Laine J., Brito J., Gallardo J., et al. J. Catal., 1985, 91(1): 64-68.