PVA/Kaolinite Nanocomposite Hydrogels: Preparation Method and Characterization

Article Preview

Abstract:

In this work, nanocomposite hydrogels on the basis of Polyvinyl alcohol (PVA) and kaolinite nanoclay were prepared by the repeatedly freezing-thawing method. The structure and morphology of nanocomposite hydrogels were studied by the XRD, TEM and SEM techniques. The function of nanoclay in the nanocomposite hydrogels was investigated using the FTIR and DSC tests. It was found that the prepared nanocomposite hydrogels have the intercalated morphology with good dispersion of nanoclay layers in hydrogel matrix. DSC results showed some shifting in the glass transition temperature of PVA hydrogel in presence of nanoclay. The FTIR results also showed that some interactions have been developed between the hydroxyl groups of PVA chains and kaolinite layers in nanocomposite hydrogels.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 383-390)

Pages:

3854-3857

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] B.V. Slaughter, S.S. Khurshid, O.Z. Fisher, A. Khademhosseini and N.A. Peppas, Hydrogels in Regenerative Medicine, Adv. Mater., Vol. 21, 2009, pp.3307-3329.

DOI: 10.1002/adma.200802106

Google Scholar

[2] J. Jagur-Grodzinski, Polymeric gels and hydrogels for biomedical and pharmaceutical applications, Polym. Adv. Technol., Vol. 21, 2010, pp.27-47.

DOI: 10.1002/pat.1504

Google Scholar

[3] S. Abdurrahmanoglu and O. Okay, Rheological behavior of polymer–clay nanocomposite hydrogels: Effect of nanoscale interactions, ,J. Appl. Polym. Sci., Vol. 116, 2010, pp.2328-2335.

DOI: 10.1002/app.31705

Google Scholar

[4] K. Haraguchi and T. Takehisa, Nanocomposite Hydrogels: A Unique Organic–Inorganic Network Structure with Extraordinary Mechanical, Optical, and Swelling/De-swelling Properties, Adv. Mater., Vol. 14, 2002, pp.1120-1124.

DOI: 10.1002/1521-4095(20020816)14:16<1120::aid-adma1120>3.0.co;2-9

Google Scholar

[5] P. Schexnailder and G. Schmidt, Nanocomposite Polymer hydrogels, Colloid Polym. Sci., Vol. 287, 2009, pp.1-11.

DOI: 10.1007/s00396-008-1949-0

Google Scholar