Synthesis and Properties of a New Type Diarylethene Bearing Benzo[b]thiophen Aryl Unit

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Abstract:

A new type photochromic diarylethene, 1-(2-methyl-3-benzothiophenyl)-2- [2-methyl-5-(3,5-difluorophenyl)-3-thienyl]perfluorocyclopentene (1o) was synthesized, and its photochromic and fluorescent properties were investigated. This compound exhibited reversible photochromism, changing from colorless to pink after irradiation with UV light both in solution and in PMMA amorphous film. In addition, the fluorescence spectra of diarylethene 1o evidently depended on the concentration in hexane.

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Advanced Materials Research (Volumes 393-395)

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1510-1513

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November 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] M. Irie: Chem. Rev. Vol. 100 (2000), p.1685.

Google Scholar

[2] H. Tian and S. Yang: J. Chem. Soc. Rev. Vol. 33 (2004), p.85.

Google Scholar

[3] K. Higashiguchi, K. Matsuda, N. Tanifuji and M. Irie: J. Am. Chem. Soc. Vol. 127 (2005), p.8922.

Google Scholar

[4] V.F. Traven, A.Y. Bochkov, M.M. Krayushkin, V.N. Yarovenko, B.V. Nabatov, S. M. Dolotov, V.A. Barachevsky and I.P. Beletskaya: Org. Lett. Vol. 10 (2008), p.1319.

DOI: 10.1021/ol800223g

Google Scholar

[5] Y. Chen, D.X. Zeng, N. Xie and Y.Z. Dang: J. Org. Chem. Vol. 70 (2005), p.5001.

Google Scholar

[6] T. Fukaminato, T. Sasaki, T. Kawai, N. Tamai and M. Irie: J. Am. Chem. Soc. Vol. 126 (2004), p.14843.

Google Scholar

[7] S.Z. Pu, F.S. Zhang, J.K. Xu, L. Shen, Q. Xiao and B. Chen: Mater. Lett. Vol. 60 (2006), p.485.

Google Scholar

[8] K. Matsuda and M. Irie: J. Photochem. Photobiol. C: Photoch. Rev. Vol. 5 (2004), p.169.

Google Scholar

[9] M. Morimoto and M. Irie: Chem. Commun. 2005, p.3895.

Google Scholar

[10] H. Dürr and H. Bouas-Laurent: Photochromism, Molecules and Systems (Elsevier Publications, Amsterdam 1990).

Google Scholar

[11] S.Z. Pu, C.B. Fan, W.J. Miao and G. Liu: Tetrahedron 64 (2008), p.9464.

Google Scholar

[12] S.Z. Pu, P.J. Yan, G. Liu, W.J. Miao and W.J. Liu: Tetrahedron Lett 52 (2011), p.143.

Google Scholar

[13] S.Z. Pu, M. Li, C.B. Fan, G. Liu, L. Shen: J. Mol. Struct. Vol. 919 (2009), p.100.

Google Scholar

[14] Z.X. Li, L.Y. Liao, W. Sun, C.H. Xu, C. Zhang, C.J. Fang and C.H. Yan: J. Phys. Chem. C, Vol. 112 (2008), p.5190.

Google Scholar

[15] S.Z. Pu, H.H. Tang, B. Chen, J.K. Xu and W.H. Huang: Mater. Lett. Vol. 60 (2006), p.3553.

Google Scholar

[16] Tyler B. Norsten, and Neil R. Branda: J. Am. Chem. Soc. Vol. 123 (2001), p.1784.

Google Scholar