Synthesis of Methacrolein by Condensation of Propionaldehyde with Formaldehyde

Article Preview

Abstract:

Methacrolein is an important intermediate in the synthesis of methyl methacrylate (MMA), which is widely used for producing acrylic plastics or producing polymer dispersions for paints and coatings. In this paper, methacrolein was synthesized by condensation of propionaldehyde with formaldehyde in the pressense of amine salt through Mannich base intermediate at the atmospheric pressure. The optimal reaction conditions were obtained. The water content in starting mixture were also investigated

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 396-398)

Pages:

1094-1097

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] K. Weissermel, H-J. Arpe, Industrial Organic Chemistry, (third ed., VCH Publishers, 1997).

Google Scholar

[2] Koichi Nagai, Appl. Catal. A Vol. 221 (2001), P. 367-377.

Google Scholar

[3] Gerd Duembgen, Dannstadt-Schauernheim; Gerd Gouquet, Neustadt; Richard Krabetz, Kirchheim, U.S. 4,496,770. (1985).

Google Scholar

[4] Deshpande, R.M., Diwakar, M.M., Mahajan A.N., & Chaudhari R.V. J. Mol. Catal. A: Chem. Vol. 211 (2004), p.49–53.

Google Scholar

[5] Zhongling Hong: Deep processing of chemical material. Chemical Industry Press in Chinese (1997).

Google Scholar

[6] Franz Merger, Frankenthal; Han-Juergen Foerster, Bobenheim-Roxheim, U.S. Patent 4,408,079. (1983).

Google Scholar

[7] H. Hellmann, Angew. Chem. Int. Ed. Vol. 68 (1956), pp.256-272.

Google Scholar

[8] M. R. Vishnumaya and V. K. Singh, J. Org. Chem. Vol. 74 (2009), pp.4289-4297.

Google Scholar