Synthesis and Crystal Structure of Copper (II) Complex Derived from N-(4,6-dimethylpyrimidin)-N’-(ethoxycarbonyl)thiourea

Ying Hui Ren; Hai Xia Ma; Kang Zhen Xu; Jie Huang; Du Bei Zhang; Ji Rong Song

doi:10.4028/www.scientific.net/AMR.396-398.2103

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HomeAdvanced Materials ResearchAdvanced Materials Research Vols. 396-398Synthesis and Crystal Structure of Copper (II)...

Synthesis and Crystal Structure of Copper (II) Complex Derived from N-(4,6-dimethylpyrimidin)-N’-(ethoxycarbonyl)thiourea

Abstract:

A new copper(Ⅱ) complex derived from N-(4,6-dimethylpyrimidin)-N’-(ethoxycarbonyl) thiourea was synthesized. The crystal is of monoclinic, P21/n, a=10.228(2), b= 11.429(2), c= 13.390(3) Ǻ, β =104.05(3)º, V=1518.3(5) Ǻ3 and Z = 2. Its crystal and molecular structure shows two N-(4,6-dimethylpyrimidin)-N’-(ethoxycarbonyl)thiourea molecules coordinate to copper(Ⅱ) through single dentate of the nitrogen atom.