Preparation and Microwave Absorption Properties of FeCoNi-EG Composites Obtained by Electroless Plating Process

Article Preview

Abstract:

FeCoNi-expanded graphite (EG) microwave absorption composites were prepared by electroless plating process. Nickel、nickel-cobalt alloy and nickel-cobalt-iron alloy were plated to the expanded graphite, and the elemental composition, structure, magnetic and microwave absorption of these composites were investigated with the use of scanning electron microscopy, X-ray diffraction, energy dispersive spectra, hysteresis loop and electromagnetic parameter analysis. The microwave absorption properties were measured in the frequency range of 2.0-18 GHz. The results show that EG is plated symmetrical magnetic metal or their alloy, it is about 70~150nm thick. The coatings deposited from an electroless bath have the transformation of amorphous phase to crystalline phase after heat treatment 1h at 400°C.The magnetism capability of these composites is enhanced compared with pure EG. The optimum matching is 3mm thick and the maximum reflection coefficient shifts to lower frequency with the increase of thickness. The absorption property of FeCoNi-EG composite after heat treatment 1h at 400°C is the best, and when it is 3mm thick, the maximum theoretical reflection loss is about -28.8dB (the matching frequency is 13.5GHz), and the absorption bandwidth below -10dB is 8GHz. The other adsorption bandwidth below -10dB for plating Ni, Ni-Co, Ni-Fe on the surface of EG were 4.2GHz, 5.2GHz and 6.5GHz, respectively.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 396-398)

Pages:

2322-2329

Citation:

Online since:

November 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] Uwe Kron, Klaus Moller, Ernest Shulz. Pyrotechnic smoke generator for camouflage purpose. U. S. Patent, 5656794. 1997. 1-5.

Google Scholar

[2] ZHOU Wei, DONG Jian. Carbon Technology [J], 2004,(4):27-28 (inChinese)

Google Scholar

[3] Kristan P.Gurton, Charles W. Bruce. Army Reserch Laboratory, 1997. 53-58.

Google Scholar

[4] Yang S Y, Lozano K,Lomeli A,et al.Composites,2005,(36):691-697

Google Scholar

[5] Yang Y,Gupta M C,Dudley K L,et al.Nano Lett.,2005,(5):2131-2134

Google Scholar

[6] ZHANG Xue-feng, LI Zhe-nan et al. Microwave absorption characteristics of ferromagnetic Fe, Co, Ni nanoparticles[J]. Powder Metallurgy Industry, 2006, 16(1): 1116.(in Chinese)

Google Scholar

[7] KIMA S S, KIMA S T, AHN J M, et al. Magnetic and micro-wave absorbing properties of Co-Fe thin films plated on hollow ceramic microspheres of low density [J]. J Magn Magn Mater, 2004, 271: 3945.

DOI: 10.1016/j.jmmm.2003.09.012

Google Scholar

[8] DUFFY D M, BLACKMAN J A, MULHERAN P A, et al. Transition metal clusters on graphite. J Magn Magn Mater[J], 1998, 181: 953-954.

DOI: 10.1016/s0304-8853(97)00757-9

Google Scholar

[9] N.K. Shrestha, D.B. Hamal, T.Saji, Surf.Coat.Technol. 183 (2004)247.

Google Scholar

[10] PENG Jun-Fang, KANG Fei-Yu. Material Science and Engineering [J], 2002, 20(4): 469-472.

Google Scholar