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Preparation and Properties of La/Ni-MoS2 Composites in Catalytic Hydrogenation of Sulfolene

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Abstract:

Effect of ultrasonic waves, premonitory LixMoS2 and La/Ni-MoS2 composites were prepared by n-butyl lithium intercalating in the MoS2 layers, using the single-molecular-layer exfoliated-restacked technology. The effect of catalyst on the performance was investigated with catalytic hydrogenation of sulfolene over composites as probe reaction. The catalyst evaluation results show that the optimum atomic ratio, hydrogen pressure and reactive temperature were n(La):n(Ni) = 0.05, 2.5 MPa and 60 °C, respectively. Under such condition, conversion of sulfolene was 99.8%, the yield of sulfolane reached 95.5%.

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Periodical:

Advanced Materials Research (Volumes 396-398)

Pages:

798-801

DOI:

https://doi.org/10.4028/www.scientific.net/AMR.396-398.798

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Online since:

November 2011

Authors:

Tai Xuan Jia, Ji Chang Zhang, Zi Li Liu

Keywords:

Catalytic Hydrogenation, La/Ni-MoS2, Sulfolane, Sulfolene

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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References

[1] J. Leonard, D. Appleton: Tetrahedron Lett. Vol.35 (1994), p.1071

Google Scholar

[2] E.S. Zhan, S. Li: Catal. Commun. Vol.8 (2007), p.1239

Google Scholar

[3] E. Klemm, B.H. Amon:Chem. Eng. Sci. Vol.56 (2001), p.1347

Google Scholar

[4] M.X. WU, W. LI, M.H. ZHANG: Chin. J. of Catal. Vol.28 (2007), p.351

Google Scholar

[5] Y.V. Zubavichus A.S. Golub: J. of Molec. Ctal. A: Chem. Vol.158 (2000), p.231

Google Scholar

[6] Benavente, M. A. Santa Ana: Coord. Chem. Rvi. Vol.224 (2002), p.87

Google Scholar

[7] J.V. Lauritsen M.V. Bollinger E.: J of Catal., Vol.221 (2004), p.510

Google Scholar

[8] W.B. YANG, L. Ai: Modern Chem. Indu. Vol.27 (2007), p.126

Google Scholar

[9] Y.H. LU, M.H. Zhang, W. Li: Petro-chem. Tech. Vol.34 (2005), p.523

Google Scholar

[10] Ching Thian Tye, Kevin J. Smith:.Catal. Tod.Vol.116 (2006), p.461

Google Scholar

[11] J.V. Lauritsen, S. Helveg: J. of Catal. Vol.197 (2001), p.1

Google Scholar

[12] B.Z. LIN, J.F. ZHANG: Appl. Catal. A: Gen. Vol.331 (2007) p.105

Google Scholar

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