Isobaric Vapor-Liquid Equilibria of Hexamethyl Disiloxane + Ethyl Acetate System at Normal Pressure

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Abstract:

Vapor-liquid equilibrium data of hexamethyl disiloxane + ethyl acetate system at 101.3kPa were measured by using double circulating vapor-liquid equilibrium still. The thermodynamic consistency of the VLE data was examined by Herrington method. Experimental data was correlated by NRTL and UNIQUAC parameter models. Both of the models satisfactorily correlated with the VLE data. The result showed that the NRTL model was the most suitable one to represent experimental data satisfactorily and the system had a minimum temperature azeotrope at 350.31 K and the mole azeotropic composition was 0.0330.

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Advanced Materials Research (Volumes 396-398)

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968-972

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November 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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