The 3d Electrons and Microdefects in Binary Ti-Al Alloys Studied by Positron Annihilation

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The behavior of 3d electrons and microdefects in binary Ti-Al alloys with Al contents from 47at.% to 53at.% have been studied by coincidence Doppler broadening and positron lifetime techniques. It has been found that the 3d electron signals in the spectra of binary Ti-Al alloys increase with Ti content. In Al-rich Ti-Al alloys, on increasing Al content, the open volume of defect on grain boundary increases while the density of free electron decreases. On the contrary, in Ti-rich Ti-Al alloys, on increasing Ti content, the open volume of defect on grain boundary decreases, and the electron density of the grain boundary increases.

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Advanced Materials Research (Volumes 399-401)

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99-102

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November 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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