Cement-Based Solidification/Stabilization of High Concentration Chromium-Contaminated Soil

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In this paper, contaminated soil collected from chromium waste landfill has been investigated, and the cement-based solidification/stabilization (S/S) of the chromium-contaminated soil was also discussed by single-factor and orthogonal experiments. The cement can effectively solidify Cr in soil, and this can be classified into three stages: slow improvement, accelerated improvement, and technically stable limit. It is technically and economically feasible when the proportion of cement is 30%–40%. Cr (VI) dissolution can be further reduced through adding up appropriate stabilizer in the cement briquette. The results of orthogonal experiments indicate that cement proportion is the most important factor of Cr S/S, then the ratio of stabilizer, and the kind of stabilizer is the least important. In analyzing the factors of cement-based S/S of the polluted soil, the optimum parameters are as follows: the ratio of cement to soil is 35% and that of FeSO4 (stabilizer) is 2.5%. Moreover, the ultimate leaching concentration of Cr (VI) is 0.89 mg/l and curing rate is 98.27%.

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232-237

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December 2011

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© 2012 Trans Tech Publications Ltd. All Rights Reserved

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[1] Cai LiYuan, Xu YouZhe, Wang HaiYing, et al. Cr(VI) remediation by Pannonibacter phragmitetus in contaminated soils, J. The Chinese Journal of Nonferrous Metals. 19 (2009) 2230-2236.

Google Scholar

[2] Liu Yuqiang, Li Li, Wang Qi. Study on Pollution Situation at Typical Chrome Residue Contaminated Sites and Corresponding Integrated Remediation Plan, J. Research of Environmental Sciences. 22 (2009) 249-253.

Google Scholar

[3] Wang Chao, Zhou Ruofan, Song Jing, et al. Study on Remediation of Sandy Soil Polluted with Chrome Residue, J. Journal of Qingdao Technological University. 31 (2010) 58-63.

Google Scholar

[4] Pei Tingquan, Wang Liao, Zhong Shan, et al. Pollution characteristics and treatment analysis of chromium residue and soil chromium in typical chromium residue simple stock, J. Chinese Journal of Environmental Engineering. 2 (2008) 994-999.

Google Scholar

[5] Q. Zhou, N.B. Milestone, M. Hayes. An alternative to Portland cement for waste encapsulation –the calcium sulfoaluminate cement system, J. Journal of Hazardous Materials. 136 (2006) 120-129.

DOI: 10.1016/j.jhazmat.2005.11.038

Google Scholar

[6] H.A. van der Sloot, A. van Zomeren, J.C. Meeussen, et al. Test method selection, validation against field data, and predictive modelling for impact evaluation of stabilised waste disposal, J. Journal of Hazardous Materials. 141 (2007) 354-369.

DOI: 10.1016/j.jhazmat.2006.05.106

Google Scholar

[7] R. Malviya, R. Chaudhary. Factors affecting hazardous waste solidification/stabilization: a review, J. Journal of Hazardous Materials. 137 (2006) 267-276.

DOI: 10.1016/j.jhazmat.2006.01.065

Google Scholar

[8] Li Yunyan. Experiment Design and Date Processing. Chemical Industry Press, Beijing, (2005).

Google Scholar

[9] X. D. Li, C. S. Poon, H. Sun, et al. Heavy metal speciation and leaching behaviors in cement based solidified/stabilized waste materials, J. Journal of Hazardous Materials. 82 (2001) 215-230.

DOI: 10.1016/s0304-3894(00)00360-5

Google Scholar

[10] C.A. Johnson, M. Kersten, F. Ziegler, et al. Leaching behaviour and solubility-controlling solid phases of heavy metals in municipal solid waste incinerator ash, J. Waste Management. 16(1996) 129-134.

DOI: 10.1016/s0956-053x(96)00036-0

Google Scholar

[11] B. Batchelor. Overview of waste stabilization with cement, J. Waste Management. 26(2006) 689–69.

DOI: 10.1016/j.wasman.2006.01.020

Google Scholar