Metal Ions Doped Complex Cobalt Blue Pigment Research

Abstract:

Metal ions doped complex cobalt blue pigments are prepared by homogeneous precipitation, to investigate the effects of doping ions Zn²⁺ ，Mg²⁺ ，Ni²⁺ and Y ³⁺ on some properties of the doped complex cobalt blue pigments, such as crystal structure, color, shading power and temperature resistance. Studies have shown that doping have little effect on the spinel crystal type and temperature resistance of the pigments ; ionic radius differences between doping ions and Co^{2 +} cause lattice distortion and changes of lattice constant , thus affecting the ligand state spaces of Co^{2 +} ion, color and shading power of complex cobalt blue pigment. The lattice constant of Zn^{2 +} doped complex cobalt blue becomes larger with the increasing amount of Zn^{2 +} ; while doping Mg^{2 +}and Ni^{2 +} , the crystal lattice constants become smaller; when doping with Y^{3 +} , Y^{3 +} ions enter into CoAl₂O₄ lattice, replacing some hexa-coordinate octahedral gap of Al^{3 +} , ionic radius differences between Y^{3 +} and Al³⁺cause lattice distortion, when doping amount of Y ^{3 +} increases to a certain extent, the phase in the form of Y₂O₃ will be generated and it will maybe form a kind of CoY_xAl_2-xO₄- Y₂O₃ solid solution instead of the complete spinel structure.

• Periodical: Advanced Materials Research (Volumes 415-417)
• Pages: 194-199
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.415-417.194
• Online since: December 2011
• Authors: Ming Quan Ye, Ai Jun Han, Zhu Bo Liu, Chen Wang
• Keywords: Complex Cobalt Blue Pigment, Doping, Homogeneous Precipitation, Lattice Distortion, Spinel

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