Probing Swelling and Shrinking Process of Polystyrene Film by In Situ Ellipsometry

Article Preview

Abstract:

We investigated the structural evolution of Polystyrene films at various conditions through multi-wavelength ellipsometry. We studied the thickness of film dependent of the process of swelling/shrinking, and the influence of the intensity of atmosphere,combining with PM (polarization microscope) to characterize the surface morphology. Results indicated that the increase and reduction of the film thickness are non-linear. Maximum swelling ratio and the variation of film thickness depend on the initial thickness of film and the intensity of atmosphere. Furthermore, the results demonstrated that in-situ multi-wavelength ellipsometry is an unique means to investigate the behavior of swelling and shrinking of film.

You might also be interested in these eBooks

Info:

Periodical:

Advanced Materials Research (Volumes 418-420)

Pages:

333-336

Citation:

Online since:

December 2011

Export:

Price:

Permissions CCC:

Permissions PLS:

Сopyright:

© 2012 Trans Tech Publications Ltd. All Rights Reserved

Share:

Citation:

[1] J. Hegewald, T. Schmidt, K. Eichhorn, K. Kretschmer, D. Kuckling, K. Arndt, Langmuir 2006, 22, 5152-5159.

DOI: 10.1021/la053461c

Google Scholar

[2] W. M. Duncan, S. A. Henck, Applied Surface Science 1993, 63, 9-16.

Google Scholar

[3] O. M. Tanchak, C. J. Barrett, Chem. Mater. 2004, 16, 2734-2739.

Google Scholar

[4] M. L. Michael, B. Giovanni, J. Nanopart. Res. 2009, 11, 1521–1554.

Google Scholar

[5] I. Zudans, C. J. Seliskar, W. R. Heineman, Thin Solid Films 2003, 426, 238–245.

Google Scholar

[6] B. Sun, Y. Lai, Y. Kim, Y. Men, Front. Chem. China 2009, 4, 265–268.

Google Scholar

[7] T. J. Halthur, P. M. Claesson, U. M. Elofsson, J. Am. Chem. Soc. 2004, 126, 17009-17015.

Google Scholar

[8] G. M. W. Kroesen, G. S. Oehrlein, T. D. Bestwick, J. Appl. Phys. 1991, 69.

Google Scholar

[9] S. M. Sirard, P. F. Green, K. P. Johnston, J. Phys. Chem. B 2001, 105, 766-772.

Google Scholar