Property of Nanoporous Metal-Organic Frameworks at Different Synthesis Temperature

Abstract:

The nanoporous metal-organic frameworks were synthesized under solvothermal conditions using organic solvent dimethylformamide. The samples were characterized by XRD, SEM, TGA, FT-IR and specific surface area for their properties difference. When the reaction temperature rises, the particle size becomes larger. All TGA curves are the basically same, the framework structure begins to be destroyed from 500°C up to around 600°C. The metal-organic frameworks accepted at reaction temperature 190°C have larger specific surface area and better structure stability.

• Periodical: Advanced Materials Research (Volume 427)
• Pages: 123-127
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.427.123
• Online since: January 2012
• Authors: Yuan Hui Ma, Lei Zhang, Cheng Chun Tang
• Keywords: Metal-Organic Framework, Property Analysis, Synthesis Temperature

References

[1] Y. G. Sun, W. Yu and L. Wang, et al.: Inorganic Chemistry Communications, 2010. 13, p.479.

[2] B. Xiao and Q. C. Yuan: Particuology, 2009. 7, p.130.

[3] Q. Zheng, H. Xu and Y. J. Cui, et al.: Materials Review, 2008. 22(11), p.106.

[4] G. Horvath and K. J. Kawazoe: J Chem Eng Jpn, 1983. 22, p.470.

[5] J. Zhang, S. S. Liu and L. F. Song, et al.: Materials China, 2009, 28(5), p.31.

[6] T. Loiseau, C. Serre and C. Huguenard, et al: Chem istry2a European Journal, 2004, 10, p.1373.