Synthesis and Application of Reactive Dyes Containing a Hydroxybenzophenone Ultraviolet Absorber

Abstract:

Novel orange reactive dyes containing a built-in benzophenone moiety had been synthesized in four steps and characterized using electrospray mass spectroscopy analysis. They were applied to dye cotton fabrics and evaluated for their ability to give protection against the harmful UV radiation. The results showed that the anti-ultraviolet properties of the dyed cotton with the dyes containing a built-in hydroxybenzophenone moiety were significantly improved. However, the incorporation of methyl or ethyl groups into the benzophenone moiety did not show a beneficial effect on the UPF values of dyed cotton.

• Periodical: Advanced Materials Research (Volume 441)
• Pages: 512-516
• DOI: https://doi.org/10.4028/www.scientific.net/AMR.441.512
• Online since: January 2012
• Authors: Liang He, Li Hua Lu, De Feng Zhao
• Keywords: Anti-Ultraviolet, Hydroxybenzophenone, Reactive Dyes

References

[1] T. Sato, N. Oku, E. Iida, K. Kawaguchi, K. Yamanaka, T. Mori, S. Okada, Differential effect of UV-B and UV-C on DNA damage in L-132 cells, Biol. Pharm. Bull. 19 (1996) 721-725.

DOI: 10.1248/bpb.19.721

[2] N. Dumaz, H.J. van Kranen, A. de Vries, R.J. Berg, P. W Wester, C.F. van Kreijl, A. Sarasin, L. Daya-Grosjean, F.R. de Gruijl, Theo role of UV-B light in skin carcinogenesis through the analysis of p.53 mutations in squamous cell carcinomas of hairless mice, Carcinogenesis. 18 (1997).

DOI: 10.1093/carcin/18.5.897

[3] B.K. Armstrong, A. Kricker, The epidemiology of UV induced skin cancer, J. Photochem. Photobiol. B. 63 (2001) 8-18.

[4] R.T. Greenlee, T. Murray, S. Bolden, P.A. Wingo, Cancer statistics, 2000, CA Cancer J. Clin. 50 (2000) 7-33.

DOI: 10.3322/canjclin.50.1.7

[5] D. Cristea, G. Vilarem, Improving light fastness of natural dyes on cotton yarn, Dyes Pigm. 70 (2006) 238-245.

DOI: 10.1016/j.dyepig.2005.03.006

[6] A.F. Strobel, Improvement of lightfastness of dyeings on synthetic fibers by ultraviolet absorbers, part II, Am. Dyest. Reptr. 51 (1962) 35-40.

[7] W. Czajkowski, J. Paluszkiewicz, R. Stolarski, M. Kaz´mierska, E. Grzesiak, Synthesis of reactive UV absorbers, derivatives of monochlorotriazine, for improvement in protecting properties of cellulose fabrics, Dyes Pigm. 71 (2006) 224-230.

DOI: 10.1016/j.dyepig.2005.07.004

[8] J. -P. Bacher, W. Kaufmann, D. Reinehr, Triazine ultraviolet absorbers useful for improving the sun protection factor of textiles, U.S. Patent 5, 741, 905. (1998).

[9] Y. Sun, G. Gong, X. Sheng, D. Zhao, Research on synthesis of 2-hydroxy-4-methoxy-3'-amino-di-benzophenone and its alkyl derivatives, J. Dalian Univ. Technol. 46 (2006) 792-796.

[10] J. Xiao, S. Zhang, J. Yang, Q. Huang, Study on chemical bonding of polycarboxylic acid black on cotton and its dyeing and finishing properties, Dyes Pigm. 73 (2007) 111-117.

DOI: 10.1016/j.dyepig.2005.10.018

[11] L. He, G. Gong, H.S. Freeman, W. Jian, M. Chen, D. Zhao, Studies involving reactive dyes containing a benzophenone ultraviolet absorber, Color. Technol. 127 (2011) 47-54.

DOI: 10.1111/j.1478-4408.2010.00277.x